The Effect of Structure on Acid-Base Properties Flashcards
What is an oxyacid/oxoacid?
Acids that contain hydrogen, oxygen and another element
1st rule for oxyacids
For any central atom, the strength increases with the number of oxygen attached
2nd rule for oxyacids
When central atoms are in same group and same number of oxygen attached..
- Strength increases from bottom to top
3rd rule for oxyacids
When same number of oxygen are attached to central atom…
- Strength increases from left to right
What else does it indicate when an atom has a good ability to draw electrons towards itself?
- The greater the acidity of the molecule
- Will be molecules with higher electronegativity
1st rule for strength of binary acids
Strength increases from left to right
2nd rule for strength of binary acids
Increases from top to bottom
What are the 2 determining factors if an H-X bond behaves as a Bronsted acid?
- Strength of the bond
- Polarity