The Atom Flashcards

Atom Intro, Periodic Table and Chemical Bonding

1
Q

Describe the structure of the atom

A
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2
Q

What is an atomic number?

A

An atomic number represents and is equal to the number of protons an element has

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3
Q

What is mass number?

A

The sum of the mass of the total number of protons and neutrons

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4
Q

What are isotopes?

A

They are the same element with a different number of neutrons that have different abundance in nature and have different properties compared to each other

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5
Q

Outline Neil Bohr’s Visualisation of The Atom

A

The atomic number (z) is equal to the total number of electrons

protons and neutrons exist in equal proportion within the nucleus of the atom

electrons exist in a cloud around the nucleus and occupy shells

the valence shell is the outermost electron shell of an atom

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6
Q

Describe “atomic radius” and its trends within the periodic table

A

Atomic radius decreases across a period, due to increasing electrostatic interaction - less distance from the nucleus

Atomic radius increases down a group, due to increased shielding from inner shells - more distance from the nucleus

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7
Q

Describe “ionic radius” and its differences from “atomic radius”

A

when electrons leave, or are added, to the valence shell of an atom they change the ratio of protons to electrons, and therefore the overall charge of the atom changes

when cations + are formed the IR is less than the AR due to a greater relative positive charge

when anions - are formed the IR is larger than the AR due to a smaller relative charge

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8
Q

Describe “ionisation energy” and its trends within the periodic table

A

Ionisation energy is the amount of energy required to remove an electron from an atom

IE is inversely proportional to AR, due to increased electrostatic attraction between protons and electrons

increases across a period and decreases down a group

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9
Q

What is “electronegativity”?

A

the ability of an atom to attract shared electrons to itself

increases along a period and decreases down a group

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10
Q

What is “electron affinity”?

A

how likely an atom is to receive an electron

ionic bonds

increases along a period and decreases down a group

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11
Q

What is the main drive for atoms to bond with one another?

A

to completely fill their valence shell as it enables greater stability

“the rule of two” - period 1 elements
“octet rule” - period 2 - 7 elements

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12
Q

What is the typical number of electrons in the valence shell of Metals?

A

0-3, so “easier” to give away electrons
typical form cations

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13
Q

What is the typical number of electrons in the valence shell of Non-Metals?

A

5-7, so “easier” to take electrons to satisfy the “octet rule”
typically anions

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14
Q

Describe “Ionic Bonds”

A

forms between a metal and a non-metal, when ¡ or more electrons are exchanged between the two

when an atom loses an electron it becomes ionized, metals form cations

when an atom gains an electron and becomes ionized, non-metals form anions

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15
Q

Describe “Covalent Bonds”

A

two non-metal bonds through the sharing of electrons (1-4) from their respective valence shells to satisfy their octet

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16
Q

Describe “Metallic Bonding”

A

forms between 2 or more metals

arises from the electrostatic attraction between metal cations and delocalised electrons

when metal atoms bond they relinquish their valence shell electrons and become ionized creating a sea of free-flowing electrons existing in and around the cations

17
Q

What characteristics does this sea of free flowing electrons enable?

A

ability to carry a charge

malleable

bending metals will not change their availability, and thus metallic bonds will remain and no break will occur (no requirement of proximity for bond to occur)

18
Q

What is an “Empirical Formula”?

A

ratio of elements within a compound

19
Q

What is a “Molecular Formula”?

A

the ratio of elements within a compound and how many total atoms of an element exist

20
Q

What is a “Structural Formula”?

A

number of bonds, and their type, as well as the total number of atoms of each element within the compound

21
Q

What formula arises from Bohr’s visualisation?

A

2n2 , where n is the no. of the shell