Tests For Ions Flashcards
Mg 2+ (aq)
Add Dil. NaOH, white ppt forms
Mg2+(aq) + 2OH-(aq) –> Mg(OH)2(s)
NH4+
Add dil. NaOH, Warm, test gas with red litmus or heat the solid
NH4+(aq) + OH-(aq) –> NH3(g) +H2O(l)
NH3, alkaline gas
NH4+ sublimes to produce a white solid further up the test tube
Cl-
1) Acidify with dil. HNO3, Add AgNO3 dropwise to the ppt. Add dil. NH3 followed by conc NH3
White ppt AgCl soluble in Dil NH3
2) Add conc. H2SO4 to solid sample
Steamy Fumes, HCl
Br-
Same as Cl-
1) Cream ppt AgBr, soluble in concert NH3
2) steamy fumes HBr, orange fumes Br2
3) add Chlorine water until no change
Solution turns brown
I-
Same as Br-
1) yellow ppt of AgI Not soluble in conc NH3
2) steamy fumes HI, black solid I2
3) Solution Turns brown
SO42-
Add BaCl2 dropwise followed by HCl sol.,
White ppt forms, BaSO4, Unchanged with HCl
CO3 2-
Add acid, test gas by bubbling through limewater,
Colourless solution, effervescence, limewater goes milky
HCO3 2-
Heat aqueous solution
Effervescence, limewater goes milky
Oxygen
Glowing splint relights
Carbon dioxide
Lime water goes milky
Ammonia
Red litmus goes blue, with HCl white smoke produced
Nitrogen dioxide
This is a brown has, blue litmus turns red
Hydrogen
Lit splint produces squeeky pop
HCl
Steamy fumes blue litmus goes red, white smoke produced with NH3, white ppt produced when bubbled through AgNO3