test 3 reagents Flashcards

1
Q

SOCl2/
CHCl3

A

CA—>acid chloride

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2
Q
  1. NaOH, H2O/
  2. RCH2X
A

CA—>ester

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3
Q

ROH/
ROH2

A

CA—>ester
acid chloride—>ester

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4
Q

RN-H

A

CA—>amide

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5
Q

H3O+

A

acid chloride—>CA
ester—>CA
nitrile—>CA
ketone—>RC=CH2
|
OH

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6
Q
  1. OH, H2O/
  2. H3O+
A

acid chloride—>CA
ester—>CA
nitrile—>CA

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7
Q

RONa/
ROH

A

acid chloride—>ester

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8
Q

RNH2

A

acid chloride—>amide

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9
Q
  1. LiAlH4, Et2O/
  2. H3O+
A

RCH2OH

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10
Q

H2O/
NaOH

A

ketone—>R-C=CH2
|
OH

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11
Q

X2/
CA

A

Ketone—>replace a ‘H’ with ‘X’

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12
Q

OH, H2O/
X2

A

Ketone—>replace a ‘H’ with ‘X

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13
Q
  1. exc. X2OH, H2O/
  2. H3O+
A

methyl ketone—>CA

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14
Q
  1. Br2, PBr3/
  2. H2O
A

CA—>CA w/ Br on adjacent carbon

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15
Q

strong base

A

A/K—>enolate ion
ester–>enolate ion
nitrile—>R-C=C=N

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16
Q

RCH2X

A

enolate ion—>R-C-C-CH2
|| ||
O R

17
Q
  1. NaOR’, R’OH
  2. R”CH2X
  3. H3O+
A

-ester—>enolate ion–>ketone w/ R
-double sided ester—>enolate ion–>CA-CH-R

18
Q

what are the strong bases

A

H-(NaH)
NH2-(NaNH2)
LDA
OH-(NaOH)
OCH3-(NaOCH3)
OEt-(NaOEt)

19
Q

what solvent does LDA go with

A

THF

20
Q

what solvent does NaH and NanH2 go with

A

pentane