Test 2 reactions Flashcards
1
Q
DMP/
CH2Cl
A
-Primary OH—>Aldehyde
-secondary OH—>Ketone
2
Q
1.DIBAH, RCH3/
2.H3O+
A
-ester—>Aldehyde
3
Q
1.KMnO4, OH, H2O/
2.H3O+
A
Ketone—>CA
4
Q
Ag2O/
NH4OH
A
-Aldehyde—>CA
-OH—>CA
5
Q
KMnO4/
H2O
A
Alkyl benzene—>CA
6
Q
Grignard reagent/
H3O+
A
-Ketone/carbonyl—>OH w/ g. reagent
-Nitrile—>C on CN becomes carbonyl, add g. reagent(forms ketone)
7
Q
1.CO2/
2.H3O+
A
Grignard reagent—>CA
8
Q
NaOH/
H2O
A
Ketone—>Diol
9
Q
NaOH, H2O/
R-X
A
CA—>ester
10
Q
H3O+
A
-Ketone—>Diol
-Nitrile—>CA
11
Q
HCN, OH
A
-Ketone—>Cyanohydrin
-Aldehyde—>Cyanohrdrin
12
Q
1.LiAlH4, Et2O/
2.H2O
A
Nitrile—>NH2
13
Q
1.LiAlH4, Et2O/
2.H3O+
A
-CA—>OH
-Nitrile—>NH2
14
Q
Secondary amine
A
-Ketone—>Enamine
-Aldehyde—>Enamine
15
Q
Primary amine
A
-Ketone—>Imine
-Aldehyde—>Imine
