Test 2 reactions

Question 1

DMP/
CH2Cl

Answer 1

-Primary OH—>Aldehyde
-secondary OH—>Ketone

Question 2

1.DIBAH, RCH3/
2.H3O+

Answer 2

-ester—>Aldehyde

Question 3

1.KMnO4, OH, H2O/
2.H3O+

Answer 3

Ketone—>CA

Question 4

Ag2O/
NH4OH

Answer 4

-Aldehyde—>CA
-OH—>CA

Question 5

KMnO4/
H2O

Answer 5

Alkyl benzene—>CA

Question 6

Grignard reagent/
H3O+

Answer 6

-Ketone/carbonyl—>OH w/ g. reagent
-Nitrile—>C on CN becomes carbonyl, add g. reagent(forms ketone)

Question 7

1.CO2/
2.H3O+

Answer 7

Grignard reagent—>CA

Question 8

NaOH/
H2O

Answer 8

Ketone—>Diol

Question 9

NaOH, H2O/
R-X

Answer 9

CA—>ester

Question 10

H3O+

Answer 10

-Ketone—>Diol
-Nitrile—>CA

Question 11

HCN, OH

Answer 11

-Ketone—>Cyanohydrin
-Aldehyde—>Cyanohrdrin

Question 12

1.LiAlH4, Et2O/
2.H2O

Answer 12

Nitrile—>NH2

Question 13

1.LiAlH4, Et2O/
2.H3O+

Answer 13

-CA—>OH
-Nitrile—>NH2

Question 14

Secondary amine

Answer 14

-Ketone—>Enamine
-Aldehyde—>Enamine

Question 15

Primary amine

Answer 15

-Ketone—>Imine
-Aldehyde—>Imine

Question 16

ROH/
ROH2+

Answer 16

Carbonyl—>di OR

Question 17

H2NNH2/
OH

Answer 17

-Carbonyl—>Reduce Carbonyl
-Nitrile—>Reduction(DB)

Question 18

PPh3
|
R—C—H

Answer 18

C==R
|

Question 19

NaCN/
DMSO

Answer 19

RX—>Nitrile

Question 20

SOCl2/
Benzene

Answer 20

Carbonyl w/ NH2—>Nitrile