Test 3 Flashcards

1
Q

What is thermal energy?

A
  • Heat.
  • The kinetic energy of random motion of particles in a substance.
  • Transfer involves random particle motion
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2
Q

What is kinetic energy?

A
  • Work.
  • Transfer involves ordered particle motion.
  • Work = force X distance
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3
Q

What is an open system?

A

When both energy and matter can transfer into and out of the system.

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4
Q

What is a closed system?

A

When only energy can transfer into and out of the system.

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5
Q

What is an isolated system?

A

When neither matter nor energy can transfer into or out of the system.

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6
Q

What is a calorimeter?

A

It is an experimental approximation of an isolated system.

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7
Q

What does change in temperature depend on? (state changes aside)

A
  • Amount of heat energy
  • Mass of the substance
  • Nature of the substance
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8
Q

What happens to temperature during a state change?

A

It remains the same until the state change is complete.

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9
Q

What is the energy formula?

A

Q = m c ΔT

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10
Q

In what direction does heat transfer?

A

Warmer objects to cooler objects.

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11
Q

What is the second energy formula?

A
  • (m1 c1 ΔT1) = m2 c2 ΔT2
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12
Q

What is the formula to calculate final temperature?

A

Tf = (Ti1 m1 c1) + (Ti2 m2 c2) /

(m1 c1) + (m2 c2)

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13
Q

What are exothermic reactions?

A

Chemical reactions that release energy.

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14
Q

What are endothermic reactions?

A

Chemical reactions that absorb energy.

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15
Q

What are two thermochemical equations to represent exothermic reactions?

A

reactants —> products ΔH = -kJ

reactants —> products + kJ

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16
Q

What are two thermochemical equations to represent endothermic reactions?

A

reactants —> products ΔH = +kJ

reactants + kJ —> products

17
Q

What is enthalpy?

A

The total of all energy (kinetic and potential) contained in a substance.

18
Q

What is bond energy?

A

The amount of energy in one mole (kJ/mol).

19
Q

What is the formula to calculate change in enthalpy?

A

ΔH = ∑ Hr - ∑ Hp

20
Q

What happens to enthalpy when particles move further apart (solid –> liquid –> gas)?

A

The enthalpy increases because energy is being added. It is an endothermic reaction.

21
Q

What happens to enthalpy when particles move closer together (gas –> liquid –> solid)?

A

The enthalpy decreases because energy is being removed. It is an exothermic reaction.