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Chemistry exam > Test 3 > Flashcards

Test 3 Flashcards

1
Q
A

E1 elimination

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2
Q
A

E2 elimination

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3
Q

Competition between Sn1 and E1

A

a good nucleophile with relatively low basility favors the SN1 reaction and a poor nucleophile favors the E1 reaction

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4
Q
A

Substitution

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5
Q
A

Addition

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6
Q
A

Dehydrohalogenation of akyl halides

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7
Q
A

cyclopropanation

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8
Q
A

elimination

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9
Q
A

epoxidation

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10
Q
A

Halogenation

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11
Q
A

Halohydrin formation

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12
Q
A

HX addition

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13
Q
A

Hydration

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14
Q
A

Hydrogenation

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15
Q
A

Hydroxylation

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16
Q
A

oxidative cleavage

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17
Q

Hydrogenation of alkanes

A
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18
Q
A

Primary alcohol

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19
Q
A

Secondary alcohol

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20
Q
A

Tertiary alcohol

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21
Q
A

Phenol

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22
Q

Which category do these belong to? (alcohols and phenols)

A

Phenols

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23
Q

Which category do these belong to? (alcohols and phenols)

A

Primary alcohols

24
Q

Which category do these belong to? (alcohols and phenols)

A

Secondary alcohols

25
Q

Which category do these belong to? (alcohols and phenols)

A

Tertiary alcohols

26
Q

CH3 OH

CH3 CH2 OH

CH2 OH CH2 OH

A

Methanol

Ethanol

Ethylene glycol

27
Q
A

Alcohol forming alkoxide ion

28
Q
A

Phenol forming alkoxide ion

29
Q
A

dehydration of alcohol

30
Q
A

Reduction of an alkene (hydrogenation)

31
Q
A

Reduction of a ketone/aldehyde to an alcohol

32
Q
A

Oxidation of an aldehyde to a carboxylic acid

33
Q
A

Reduction of a carboxylic acid to an alcohol

34
Q
A

oxidation of alcohol to a ketone

35
Q

R- and Ar- for?

A

R- alkyl group
Ar- aryl group (aromatic ring)

36
Q
A

Ketone, ends in -CO

37
Q
A

Aldehyde, ends in -CHO

38
Q
A

base-catalyzed keto-enol tautomerism

39
Q
A

acid-catalyzed keto-enol tautomerism

40
Q
A

disulfide reduced to a thiol

41
Q
A

thiol oxidized to disulfide

42
Q
A

Aldol reaction

43
Q
A

Imine schiff base creation

44
Q
A

Addition of nucleophile to carbonyl groups

45
Q
A

Formation of acetals, in the case of the ketone -> common name = ketal

46
Q

HCO2H

CH3 CO2 H

CH3 CH2 CO2 H

CH3 CH2 CH2 CO2 H

A

Carboxylic acids
Common: - IUPAC:
Formic acid - methanoic acid

Acetic acid - ethanoic acid

propionic acid - propanoic acid

butyric acid - butanoic acid

47
Q

HOOC - COOH

HOOC - CH2 - COOH

HOOC - CH2 - CH2 - COOH

HOOC - CH2 - CH2 - CH2 - COOH

HOOC - CH = CH - COOH (cis)

HOOC - CH = CH - COOH (trans)

A

dicarboxylic acids
oxalic

malonic

succinic

glutaric

maleic

fumaric

48
Q
A

Acyl groups
Formyl

acetyl

propionyl

49
Q
A

Nucleophilic acyl substitution

50
Q
A

esterification

51
Q
A

Hydroxyl-carboxylic acids

  1. Lactic acid
  2. tartaric acid
  3. citric acid
52
Q
A

b-lactam ring

53
Q

what are all these?

A

Lactones

54
Q

which one is the most oxidized and which one is the most reduced?

A
55
Q

HCHO

CH3 CHO

CH3 CH2 CHO

CH3 CO CH3

H3C CH2 CO CH3

H3C CH2 C=O CH2 CH3

A

Common - IUPAC
Formaldehyde - Methanal

Acetaldehyde - Ethanal

Propionaldehyde - Propanal

Acetone - Propanone

Ethyl methyl ketone - butanone

Diethyl ketone - pentan-2-one

Chemistry exam (9 decks)

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