Test 3 Flashcards
1
Q
A
E1 elimination
2
Q
A
E2 elimination
3
Q
Competition between Sn1 and E1
A
a good nucleophile with relatively low basility favors the SN1 reaction and a poor nucleophile favors the E1 reaction
4
Q
A
Substitution
5
Q
A
Addition
6
Q
A
Dehydrohalogenation of akyl halides
7
Q
A
cyclopropanation
8
Q
A
elimination
9
Q
A
epoxidation
10
Q
A
Halogenation
11
Q
A
Halohydrin formation
12
Q
A
HX addition
13
Q
A
Hydration
14
Q
A
Hydrogenation
15
Q
A
Hydroxylation
16
Q
A
oxidative cleavage
17
Q
Hydrogenation of alkanes
A
18
Q
A
Primary alcohol
19
Q
A
Secondary alcohol
20
Q
A
Tertiary alcohol
21
Q
A
Phenol
22
Q
Which category do these belong to? (alcohols and phenols)
A
Phenols
23
Q
Which category do these belong to? (alcohols and phenols)
A
Primary alcohols
24
Q
Which category do these belong to? (alcohols and phenols)
A
Secondary alcohols
25
Which category do these belong to? (alcohols and phenols)
Tertiary alcohols
26
CH3 OH
CH3 CH2 OH
CH2 OH CH2 OH
Methanol
Ethanol
Ethylene glycol
27
Alcohol forming alkoxide ion
28
Phenol forming alkoxide ion
29
dehydration of alcohol
30
Reduction of an alkene (hydrogenation)
31
Reduction of a ketone/aldehyde to an alcohol
32
Oxidation of an aldehyde to a carboxylic acid
33
Reduction of a carboxylic acid to an alcohol
34
oxidation of alcohol to a ketone
35
R- and Ar- for?
R- alkyl group
Ar- aryl group (aromatic ring)
36
Ketone, ends in -CO
37
Aldehyde, ends in -CHO
38
base-catalyzed keto-enol tautomerism
39
acid-catalyzed keto-enol tautomerism
40
disulfide reduced to a thiol
41
thiol oxidized to disulfide
42
Aldol reaction
43
Imine schiff base creation
44
Addition of nucleophile to carbonyl groups
45
Formation of acetals, in the case of the ketone -> common name = ketal
46
HCO2H
CH3 CO2 H
CH3 CH2 CO2 H
CH3 CH2 CH2 CO2 H
Carboxylic acids
Common: - IUPAC:
Formic acid - methanoic acid
Acetic acid - ethanoic acid
propionic acid - propanoic acid
butyric acid - butanoic acid
47
HOOC - COOH
HOOC - CH2 - COOH
HOOC - CH2 - CH2 - COOH
HOOC - CH2 - CH2 - CH2 - COOH
HOOC - CH = CH - COOH (cis)
HOOC - CH = CH - COOH (trans)
dicarboxylic acids
oxalic
malonic
succinic
glutaric
maleic
fumaric
48
Acyl groups
Formyl
acetyl
propionyl
49
Nucleophilic acyl substitution
50
esterification
51
Hydroxyl-carboxylic acids
1. Lactic acid
2. tartaric acid
3. citric acid
52
b-lactam ring
53
what are all these?
Lactones
54
which one is the most oxidized and which one is the most reduced?
55
HCHO
CH3 CHO
CH3 CH2 CHO
CH3 CO CH3
H3C CH2 CO CH3
H3C CH2 C=O CH2 CH3
Common - IUPAC
Formaldehyde - Methanal
Acetaldehyde - Ethanal
Propionaldehyde - Propanal
Acetone - Propanone
Ethyl methyl ketone - butanone
Diethyl ketone - pentan-2-one
