Test 2 Flashcards
Primordial Soup Theory:
theory of origin of life on earth; described a possibility for where life originated (organic molecules from salt water)
Water makes up: (2)
states/importance
- 70% of Earth
- 70% of human body
- solid, liquid, and gas
- almost universal solvent
Structure of Water:
- polar molecule
- forms hydrogen bonds (in all 3 states)
- covalent bonding
(H-bonds: S > L > G)
Definitions:
Cohesion
Adhesion
Surface Tension:
- cohesion: linking of same molecules through hydrogen bonds (water ^ in plants)
- adhesion: attraction between different substances (water to plant cell walls)
- surface tension: measure of the force necessary to bend or break the surface of a liquid
4 Major Properties of H2O:
- cohesion/adhesion
- Temperature Moderation
- Floating of Ice
- Solvent of Life
Bodies of Water:
moderate temperature by releasing heat to cooler air and absorbing heat from warmer air; can absorb/release large amounts of heat without significant change due to its high specific heat (attempts to gain an equilibrium; cools through evaporative cooling)
Definitions: Heat: Temperature: Specific Heat: Heat of Vaporization:
- heat: measure of total kinetic energy due to molecular movement
- temperature: measure of intensity due to average kinetic energy
- specific heat: amount of heat required to heat 1g of a substance 1 deg C
- heat of vaporization: amount of heat required to vaporize 1g of a liquid
Why Does Ice Float?
Why is this important?
- ice has maximum number of H-bonds, it is more ordered, and less dense than liquid h2o
- this is important because, if ice sank, all bodies of water would eventually freeze over
Definitions: solution solute solvent aqueous solution colloid
- mixture of 2 or more substances (liquid)
- substance that is dissolved in a solvent
- a liquid in which a solute is dissolved
- when water is the solvent
- suspended fine particles (i.e. not clear)
Hydration Shell:
- h2o breaks up ionic bonds and forms a shell around each ion due to charge attractions (dissolves)
Hydrophilic vs Hydrophobic
Hydrophilic: affinity for water (ionic, polar covalent)
Hydrophobic: lacks affinity for water (non-polar covalent; lipids)
Acids and Bases (pH)
Buffers:
- acid: donates proton (H+)
- base: accepts proton (P+)
- pH: high - basic, low - acidic, 7- neutral
- buffers regulate pH and help resist changes in pH (acid-base pairs)
Carbon:
- backbone of life (large, diverse molecules)
- simple to complex molecules
Carbon: Valence Shell and Bonding
- 4 valence e-
- forms covalent bonds
- can bond with large variety of molecules
Carbon Skeletons Vary due to:
- length
- branching points
- double bonds
- cyclohexane structures
Hydrocarbons:
2
- made of H and C
- release large amounts of energy (fossil fuels)
Isomers:
definition; 3 types
- compounds that have the same molecular formula but differ structurally
1. cis/trans
2. structural
3. enantiomers
Structural Isomer:
Cis/Trans Isomer:
Enantiomer:
- different structural arrangement of atoms
- same or opposite sides of a carbon
- nonsuperimposable mirror image
Enantiomers:
- important pharmaceutically
- usually only 1 isomer is biologically active
- organisms are very sensitive to subtle variations
Functional Groups:
- function to make organic molecules more soluble
Hydroxyl: (3)
- -OH
- alcohols
- polar; hydrogen bonding
Carbonyl: (1; 2 types)
- carbon-oxygen double bond
- aldehydes: at end of skeleton
- ketones: in middle of skeleton
Carboxyl: (2)
- COOH
- carboxylic acids (donates H+)
Sulfhydryl: (4)
- SH
- thiols
- amino acid - cysteine
- stabilizes proteins
Phosphate: (2)
- -OPO32-
- contribute negative charge/release energy
ATP:
adp/atp: 1
- adenosine triphosphate: primary energy transferring molecule in our cells (atp - catabolic; releases energy adp - anabolic stores energy)
Methyl
- -CH3
- NOT POLAR
- important in sex hormones/gene expression
Definitions Macromolecules Carbohydrates Lipids Proteins Nucleic Acids *
- large molecules composed of thousands of COVALENTLY connected atoms
- fats, phospholipids, and steroids
- proteins: enzymes and many more
- nucleic acids: DNA and RNA
- structure and function are inseparable*
Polymers (2- 1=3) and Monomers
- polymer: long molecule consisting of many similar building blocks (covalent)
- carbohydrates, proteins, nucleic acids
- monomers: small, similar building blocks
Dehydration vs Hydrolysis
Dehydration: removing water in order to free electrons in order to form polymers
Hydrolysis: using water to break a polymer up into monomers