Test #2 Flashcards
5 inputs of CO2 to water
- rain (picked up from air)
- water trickling through organic soil
- subterranean water
- respiration of organisms
- decomposition at the bottom of the lake
Which isotope of Carbon is common?
12C
What percent of carbon content is 12C?
98.9%
Which isotope of Carbon is rare?
13C
Which isotope of Carbon is rare and radioactive?
14C
Which isotope of Carbon do photosynthesizers preferentially pick up?
12C
Which isotope of carbon do anaerobic metabolizers preferentially pick up?
13C
Where and how is C14 formed?
high altitudes by cosmic radiation
What is pH an abbreviation for?
power of hydrogen
What is the equation for the small fraction of water dissociating?
H20 <> H+ + OH -
When does H+ = OH-
in pure water
What is the pH and temperature of neutral water?
7, 24 degrees C
negative of the base 10 logarithm of the H+ ion
pH
pH equation
-log [H+]
What is H+ called?
hydrogen ions or protons
What is the range of pH?
0-14
What is a neutral pH?
7
pH <7
acid (acidic)
pH >7
base (alkaline)
What is the pH of most waterways?
6-9
What multiplier does acidity go by from neutral (7)
x10
2 indicators of changing pH
- color change
- electrodes
What does CO2 dissolve in natural waters as?
carbonic acid (H2CO3)
Equation for carbonic acid dissociating bicarbonate and hydrogen ions
H2CO3 > HCO3- + H+
pH of rain water
5.6
what does the pH of water come from?
CO2 picked up in the atmosphere
what extra thing can rain pick up extra hydrogen ions from
pollution
What phenomenon happens when rain water picks up extra hydrogen ions?
acid rain
What does acid rain cause?
fish mortality
What causes pollution from industry burning fossil fuels?
human activity
Equation for sulfurous acid
SO2 + H2O > H2SO4
Equation for nitrous acid
NO2 + OH- > HNO3
What produces sulfur dioxide?
volcanoes
Equation for carbonic acid producing H+
H2CO3 <> HCO3- + H+
Equation for sulfuring acid producing H+
HSO3 + H+
What does edaphic mean?
from the soil
What is strip mining?
surface mining of coal
What does strip mining contain large amounts of?
pyrite
Chemical formula of pyrite
FeS2
What happens to pyrite in an edaphic environment?
oxidized to H2SO4
What is H2SO4
sulfuric acid
What does sulfuric acid do to rivers and streams?
causes them to acidify
What is true of edaphic volcanic lakes?
very low pH due to sulfur
How extreme can the pH of volcanic lakes be?
2
What is the 2nd thing that can happen to volcanic lakes?
high pH due to sodium carbonate (=soda lakes)
How extreme can the high pH of volcanic lakes be?
9-12
Sodium carbonate dissociation equation?
Na2CO3 > Na+ + NaCO3-
What can sodium carbonate soak up?
H+
What is sodium carbonate used in?
glass manufacturing
What do edaphic anaerobic sediments at the bottom of lakes have?
bacteria producing H2S
What does H2S smell like?
rotten eggs
What does H2S lead to?
H2SO4 <> HSO3+ + H+
What do edaphic soil particles blown in the wind have?
dust containing calcareous particles
What does calcareous mean?
calcium based
What do calcareous particles do?
neutralize acid rain
What do prairies naturally have more of?
dust
What does it mean that prairies have more dust?
their waterways have less problems with acid rain
How does acidity affect oligotrophic or dystrophic lakes?
decomposition is inhibited
What is the relationship between CO2 and acid salts?
half-bound to form
What are the acid salts in water?
bicarbonates (X(HCO3)2)
What is the relationship between CO2 and neutral salts?
bound to form
What are the neutral salts in water?
carbonates (XCO3)
What is the free dissolved gas in water?
CO2
What does photosynthesis do in water?
removes the free CO2
What does photosynthesis removing the free CO2 do to the water?
raises pH
What does respiration do?
adds free CO2
What does free CO2 do to the water?
lowers pH
What are buffers?
solutions that resist change in hydrogen ion concentration when an acid or base is added
What is alkalinity?
buffering system of water
What do carbonic acid and its resulting salts do in water?
act as a buffer
What do well buffered lakes do?
resist change in pH
What are vernal pools?
temporary wetland filled with snowmelt or rain
Are vernal pools well buffered?
no
What does it mean that vernal pools are not well buffered?
acid rain can cause big fluctuations in pH and make them unsuitable for amphibians
Where are diel changes in alkalinity negligible?
dilute waters
Where have small pools been seen to have huge diel swings in pH?
the desert
What specific location has been seen to have huge diel swings in pH?
Sandusky Bay where there are huge algal blooms
What causes the algal blooms in Sandusky Bay?
huge input of CO2 during the day from photosynthesis
What happens in Sandusky Bay at night?
respiration only
What are the major anions in inland waters?
CO3 2-, SO4 2-, Cl-
What are the major cations in inland waters?
Ca 2+, Mg 2+, Na+, K+
What is total solids number in inland waters made up of?
total suspended solids and total dissolved solids
How are total suspended solids (TSS) determined?
2 micrometer filter
How are total dissolved solids (TDS) determined?
passes through
What is the average TDS in rivers?
120 ppm
What is the TDS in oligotrophic Waldo Lake, OR?
1-5.5 ppm
What is the TDS in eutrophic Lake Itasca, MN?
185 ppm
What is the TDS in seas?
35000 ppm
What is the TDS in the Great Salt Lake, UT?
220,000 ppm
What is the TDS in Great Slave Lake, Canada?
160 ppm
What is the Great Slave Lake fed by?
the Slave River
What does the Slave River contribute to Great Slave Lake?
54000 metric tons of dissolved matter per summer day and 36000 tons of suspended silt per summer day
What activity occurs in Great Slave Lake?
some commercial fishing
What is the TDS of Great Bear Lake?
98 ppm
What is the Great Bear Lake ppm so low?
no comparable input of drainage area to Great Slave Lake, more oligotrophic, no commercial fishing
What is the shortcut to measuring TDS?
measure conductance (conducting)
What does conductance measure?
flow of electrons through water
Is distilled water a good conductor?
no
What salinity should not be used to measure conductance?
above 5%
What is the ion concentration in soft water lakes?
low
What is the ion concentration in hard water lakes?
high
What ions are present in lakes with high ion concentration?
Ca and Mg
What is the most common anion in dilute freshwater (humid)
Carbonate (CO3 2-)
What does DIC stand for?
dissolved organic carbon
What is the most common form of carbonate?
bicarbonate ion with calcium (Ca(CO3)2)
What other cations can carbonate combine with?
Magnesite (MgCO3), Dolomite (CaMg(CO3)2)), BaCO3, SrCO3, K2CO3, Na2CO3- magnesium, N/A, barium, strontium, potassium, sodium
What is the chemical formula for carbonate?
CO3 2-
What is the chemical formula for sulfate?
SO4 2-
How common is sulfate?
2nd most common anion
What are the atmospheric sources of sulfate?
volcanoes, industry, sea spray
What types of industry contribute to sulfate abundance?
coal combustion, copper smelting, and paper manufacturing
What are lakes near oceans and industry higher in?
sulfur
What do edaphic (soil) sources include?
old marine deposits
What are thioplasts?
organisms adapted in anaerobic, low pH habitats with lots of sulfur
What are the sulfur reducers?
CaSO4 + organic carbon > CaS+ 2CO2 + ATP
What are the sulfur oxidizers?
some can make their sugars (similar to photosynthesis), CO2 + 2H2S + light > CH2O + H2O +2S
What is the chemical formula of chloride?
Cl-
How common is chloride?
3rd most comon anion
Where is chloride most abundant?
seas and desert pools
What compounds does chloride form?
NaCl, MgCl2