Terminologies Flashcards
System (definition and types)
Portion of universe being studied
A. Open system- transfer of matter and energy
B. Closed-transfer of energy
C. Isolated-no transfer of matter or energy
Surroundings
Portion of universe other than the system
Boundary
Real/imaginary or fixed/moving surface that separates the ststem from its surroundings and where exchange of matter and energy takes place
Diathermic boundary
Thermally-conducting boundary. Change of state is observed when two objects of diff temp is brought into contact
Adiabatic boundary
A thermally-insulating boundary in wc no change of state is observed even when two objects of different temperatures come into contact.
Equilibrium state
State in which
a. Properties of a system do not vary with time
b. System is uniform. No internal heat, work, temp, pressure, concent or velocity gradient
c. Net flows of heat, mass, or work is zero
d. Net rate of chemical reactions is zero
Mechanical Equilibrium
State that exists between two subsystems of equal pressure
Thermal Equilibrium
State that exists between two subsystems of equal temperature
Process
Any change that undergoes within a sustem that causes shift from obe equilibrium state to another
Types of process
A. Quasi-static process- slow process, system internally adjusts
B. Steady-flow- fluid flows through a controlled volume. Properties remain constant.
C. Adiabatic process- thermodynamic process in which net rate of heat transfer is zero
D. Isothermal process- process that occurs at constant temperature
E, Isobaric process- process that occurs at constant pressure
F. Isochoric/isometric process- occurs at constant volume
State or Point Functions
Functions that depend on the current state of the system and not on how the system reaches the state
Path Functions
Functions that depend on the path followed during the process.
The Zeroth Law of Thermodynamics was formulated by
Ralph Howard Fowler
The Zeroth law of thermodynamics states that
if body A is in thermal eq with body B and body B is in thermal eq with body C, then body A is in thermal eq with body C