temperature Flashcards
Van’t hoff equation
Q10 = (k2/k1)^(10/[t2-t1])
k2 and k1 = rates of the rxn at temperatures at t2 and t1
for rxn at exactly 10C: Q10=k2/k1
for a 10C change in T, most chemical rxn rate….
doubles or triples
2 thermal strategies
tolerance (body temp can vary w/ ambient temp)
regulation (body temp does not vary with ambient temp)
total thermal energy equation
dHtotal = dHmetabolism + dHconduction + dHconvection + dHradiation + dHevaporation
d=delta
H=heat
heat transfer mechanisms
conduction: direct contact
radiation: electromagnetic radiation
convection: moving medium (air/water)
evaporation: latent heat of evaporation (heat loss only)
what is the role of anatomy and behaviour in heat transfer
anatomy: surface area + surface insulation affects rates of heat exchange; respiratory organs are better at transferring heat than O2
behaviour: can alter rates of heat exchange (move to a different environment, rest, etc)
what is thermal conductivity?
what happens to heat if there is high conductivity?
formula
ability of heat energy to move within a material
high conductivity (move heat easily) = poor insulation
Fourier’s law: Q=lambda deltaT/L
Q=heat flux
lambda= thermal conductivity
deltaT=temp gradient
L=distance over which gradient extends
what is heat capacitance?
what does it influence?
ability to store heat energy (water can store more heat than air)
influence: life in water vs. air, insulation materials, behaviour
what is something that influences ALL aspects of heat exchange?
surface area to volume ratio
high ratio= high rates of heat exchange
ratio decrease w/ body size
large animals exchange heat more slowly than small snimals
what is Bergmann’s rule
mammals and birds living in cold environments tend to be larger
larger animal-> smaller area to volume ratio-> exchange/lose heat more slowly
what is Allen’s rule
mammals and birds in colder climates have smaller extremities (smaller appendages)
what else can be done to help exchange heat (2)
body posture-> alter exposed surface area
huddling reduces effective surface area
thermal strategies (4)
poikilotherm: variable body temp
homeotherm: stable body temp
ectotherm: environment determines body temp
endotherm: generates internal heat
temporal and regional endothermy
temporal heterotherms: changes over time (hibernating animals)
regional heterotherms: body temp varies in regions of body
what is regional endothermy?
localized warming of red skeletal muscle used for sustained locomotion
heat produced by red muscle is retained there
countercurrent arrangement of arterioles and venules transmits heat from venous to arterial blood retaining heat
significance of regional endothermy
allow faster contraction frequencies
how does heater tissue in billfish eye provide regional endothermy
action potential-> activates Ca2+ release into cytosol from sarcoplasmic reticulum-> sarcoplasmic reticulum takes Ca2+ back up but needs ATP-> producing ATP generates heat
thermal zones of homeotherms
thermoneutral zone: range of temp optimal for physiological processes, metabolic rate minimal
upper crit temp: metabolic rate increases as animal induces physiological response to prevent overheating
lower crit temp: metabolic rate increases to increase heat production