SYNTHETIC ROUTES - ALIPHATIC, AROMATIC, PHENOLS Flashcards
What are the reagents and conditions needed to turn an Alkane into a haloalkane
Halogen eg. Bromine
UV
What are the reagents and conditions needed to turn an Haloalkane into an alcohol
NaOH
What are the reagents and conditions needed to turn an Primary Alcohol into an aldehyde
K2Cr2O7
Distillation
What are the reagents and conditions needed to turn an Primary Alcohol into a Carboxylic acid
K2Cr2O7/ H2SO4
Reflux
What are the reagents and conditions needed to turn an Aldehyde into a carboxylic acid
K2Cr2O7 / H2SO4
Reflux
What are the reagents and conditions needed to turn an carboxylic acid into an acyl chloride
SOCl2
What are the reagents and conditions needed to turn an Acyl chloride into a carboxylic acid
H2O
What are the reagents and conditions needed to turn an Aldehyde into a primary Alcohol
NaBH4
What are the reagents and conditions needed to turn an Alcohol into a haloalkane
Sodium Halide / H2SO4
What are the reagents and conditions needed to turn an Alcohol into a Alkene
H3PO4 or H2SO4
Heat
What are the reagents and conditions needed to turn an Alkene into an Alcohol
H2O (Steam)
H3PO4
What are the reagents and conditions needed to turn an Alkene into a haloalkane
Hydrogen Halide
What are the reagents and conditions needed to turn an Alkene into an alkane
H2 / Ni
What are the reagents and conditions needed to turn an Alcohol into an Ester
Carboxylic acid / Conc. H2SO4
OR
Acid Anhydride
What are the reagents and conditions needed to turn an Ester into a carboxylate
OH-
Heat
What are the reagents and conditions needed to turn an ester into a Carboxylic acid
Dilute acid
Heat
What are the reagents and conditions needed to turn an carboxylic acid into an Ester
Alcohol / Conc. H2SO4
What are the reagents and conditions needed to turn an Acyl Chloride into an ester
Alcohol
What are the reagents and conditions needed to turn an acyl chloride into a primary amide
NH3
What are the reagents and conditions needed to turn an acyl chloride into a secondary amide
Primary amine
What are the reagents and conditions needed to turn a haloalkane into a Nitrile
CN- / Ethanol
What are the reagents and conditions needed to turn a haloalkane into a Amine
NH3 / Ethanol
What are the reagents and conditions needed to turn a nitrile into an amine
H2 / Ni
What are the reagents and conditions needed to turn a nitrile into a Carboxylic acid
H2O / HCl
Heat
What are the reagents and conditions needed to turn an hydroxynitrile into an Amine
H2 / Ni
What are the reagents and conditions needed to turn a Ketone into a Hydroxynitrile
NaCN (aq)
H+ (aq)
What are the reagents and conditions needed to turn a secondary alcohol into a Ketone
K2Cr2O7 / H2SO4
Reflux
What are the reagents and conditions needed to turn a Ketone into a secondary alcohol
NaBH4
What are the reagents and conditions needed to turn an Aldehyde into a Hydroxynitrile
NaCN (aq)
H+ (aq)
What are the reagents and conditions needed to turn a hydroxynitrile into a carboxylic acid
H2O / HCl, Heat
What are the reagents needed to turn benzene into methyl-benzene
CH3Cl / AlCl3
What are the reagents needed to turn benzene into bromobenzene
Br2 / AlBr3 or Fe or FeBr3
What are the reagents needed to turn benzene into Chlorobenzene
Cl2 / AlCl3 or Fe or FeCl3
What are the reagents needed to turn benzene into nitrobenzene
Conc. HNO3
Conc H2SO4
What are the reagents needed to turn benzene into acetophenone
CH3COCl
AlCl3
What are the reagents needed to turn Acetophenone into 1-phenylethanol
NaBH4
What are the reagents needed to turn nitrobenzene into Phenylamine
Sn/conc. HCl
What are the reagents needed to turn phenylamine into 2,4,6-Tribromophenylamine
Br2
What are the reagents needed to turn Phenol into 2,4,6-Tribromophen ol
Br2
What are the reagents needed to turn Phenol into Sodium phenoxide
NaOH (aq)
What are the reagents needed to turn Phenol into either 2-nitrophenol or 4-nitrophenol
Dilute HNO3