Synthetic Routes Flashcards
ALKENE –> ALKANE
Reduction / Hydrogenation
H2 and Ni catalyst
ALCOHOL –> ALKENE
conc H2SO4
ALKENE –> ALCOHOL
Hydration
H3PO4/H2O
ALKANE –> HALOALKANE
Radical substitution
UV light/halogen
ALKENE –> HALOALKANE
Electrophilic addition
Hydrogen halide
ALCOHOL –> HALOALKANE
Nucleophilic substitution
Na halide/H2SO4
HALOALKANE –> ALCOHOL
Nucleophilic substitution
NaOH
HALOALKANE –> AMINE
NH3 dissolved in ethanol
HALOALKANE –> NITRILE
NaCN
PRIMARY ALCOHOL –> ALDEHYDE
Oxidation [O]
Distillation
K2Cr2O7/conc H2SO4
SECONDARY ALCOHOL –> KETONE
Oxidation [O]
Reflux
K2Cr2O7/H2SO4
PRIMARY ALCOHOL –> CARBOXYLIC ACID
Oxidation 2[O]
Reflux
K2Cr2O7/H2SO4
ALDEHYDE –> PRIMARY ALCOHOL
Reduction
NaBH4/H2O
ALDEHYDE –> CARBOXYLIC ACID
Oxidation
K2Cr2O7/H+
ALDEHYDE –> HYDROXYNITRILE
Nucleophilic addition
NaCN/H+