surface properties exam 1 Flashcards

1
Q

what are surface properties equally important as

A

bulk properties - can be very different due to unbalanced interactions

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2
Q

where do most biological responses occur

A

on the interface between biomaterials and biological systems at molecular (nano) and cellular (micro) levels

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3
Q

what does attenuation (reduction) of bonding lead to

A

unfulfilled strong and weak interactions

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4
Q

why do molecules/atoms on the surface have excess free energy

A

because of unbalanced interfacial/surface forces

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5
Q

what has a high surface energy

A

corners and tips because there are random shapes and higher area

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6
Q

how is critical surface tension (CST) determined

A

by dropping a series of liquids of known surface tension on the unknown biomaterial surface for extrapolation

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7
Q

what does the Zisman theory define

A

the surface tension of a solid material as being = to the surface tension of the highest (or lowest) surface tension liquid that wets the solid material surface completely

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8
Q

what does a goniometer do

A

camera takes picture of image and software takes measurements over time to determine contact angle

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9
Q

what is cst

A

critical surface tension - highest surface tension with a 0 degree angle where liquid wets solid material completely

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10
Q

what is the sliding angle

A

tells how sticky a surface is; low sliding area = easier to move slides

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11
Q

what does contact angle show

A

how strong water repellent properties are - better CA = better performance

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12
Q

what are mechanical surface properties

A

interfacial/surface tension, modulus, wear resistance

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13
Q

what are chemical surface properties

A

hydrophobicity/hydrophilicity, composition, interfacial/surface energy, reactivity, corrosion resistance

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14
Q

what are topographical properties

A

roughness, morphology/shape, curvature

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15
Q

what are electrical properties

A

charge density, electron density

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16
Q

what are optical properties

A

absorption, reflection, scattering

17
Q

what is the resolution power between light microscopy, AFM, and TEM/SEM

A

light microscopy < TEM/SEM < AFM

18
Q

when is confocal microscopy used

A

for fluorescence only

19
Q

how is surface tension measured and determined

A

measured by contact angle goniometry (smaller = more hydrophilic) and determined by Zisman method

20
Q

how are biomaterial surface properties analyzed

A

various spectroscopy and microscopy techniques

21
Q

what are dynamic light scattering instruments used for

A

to measure the size of particles and their surface zeta potential