Surface Chemistry Flashcards

1
Q

2KClO3——– 2KCl + 3O2 catalyst used

A

MnO2

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2
Q

2SO2 (g) ——–2 SO3 (g)

A

platinum

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3
Q

catalyst used in ostwald’s process

A

platinum gauze

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4
Q

CO+3H2 ——– product formed when Ni is used as catalyst

A

methane CH4

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5
Q

CO + 2 H2 ———- CH3OH catalyst used is

A

Cu/ZnO- Cr2O7

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6
Q

CO+H2 ——– Formaldehyde (HCHO) catalyst used

A

copper

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7
Q

Zeolites catalyst is made up

A

Aluminumsilicates

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8
Q

zeolite used in peroleum industry

A

ZSM-5

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9
Q

C12H22O11 + H2O ———— Glucose +Fructose enzyme used

A

invertase

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10
Q

C6H12O6 ———– C2H5OH enzyme involved is

A

Zymase

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11
Q

Starch ——— Maltose enzyme used

A

Diastase

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12
Q

contact process for manufacture of sulfuric acid the catalyst used is

A

platinum or V2O5

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13
Q

paints and cell fluids are ———– colloid

A

solid liquid

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14
Q

cheese butter is ———– colloid

A

Liquid solid (dispersed phase and dispersion medium) called as gel

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15
Q

Milk and hair cream is —————-colloid

A

Emulsion (liquid liquid)

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16
Q

Smoke is Solid in gas colloid where as Fog mist and insecticide spray is

A

Liquid in gas

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17
Q

pumice stone and foam rubber is ———– colloid

A

gas in solid (solid sol)

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18
Q

froth, soap, whipped cream are —————— colloids

A

Gas in liquid (foam)

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19
Q

colloids with alcohol as dispersion medium are called

A

Alcosol

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20
Q

lyophilic sols do not undergo coagulation true or false

A

true

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21
Q

size of multimolecular colloids is

A

less than 1nm

22
Q

Few stong electrolytes form colloids above a particular concentration called as

A

critical micelle concentration (CMC)

23
Q

micelle formation takes place above particular temperature called as

A

Kraft temperature

24
Q

CMC of soap is

A

10-4 to 10-5 mol L-1

25
As2O3 on reaction with H2S gives a colloid whose formula is
As2S3
26
H2S gets oxidised by SO2 to form a substance which forms colloid in water. the substance is
sulfur
27
AuCl3 is reduced by formaldehyde (HCHO) to form a colloid in water the reaction is
AuCl3 +HCHO+H2O---------- Au+HCOOH+HCl
28
FeCl3 is hydrolysed to ------------ which form a colloid
Fe(OH)3
29
Colloidal sols of Au, Ag and Pt are generally prepared by
Electrical disintegration or Bredig's Arc method
30
precipitate is converted to colloidal sol by
peptisation (by using peptizing agent)
31
Colloidal solutions are stabilized by small amounts of --------
electrolytes
32
Pore size of filter paper can be reduced by use of-----------------
Colloidon solution eg 4% solution of nitro cellulose in mixture of alcohol and ether.
33
ultramicroscope works on principle of ------------------
tyndall effect
34
Mixture milk and water appears blue when viewed by----------- and red when viewed by ------------------
reflected light | transmitted light
35
Haemoglobin sol carries ------------- electrical charge
positive
36
Sols of metallic oxides carry -------charge where as metallic sulfides carry -------- charge
positive | negetive
37
Sols of starch, gum gelatin, clay and charcoal carry -------charge
negetive
38
metals sols carry ----------- charge
negetive
39
basic dye stuffs like methylene blue sols carry------------ charge whereas acidic dye stuffs eg eosin, congo red sols carry --------charge
positive | negetive
40
Addition of AgNO3 solution to KI solution what is the resulting colloid
AgI/I- negetively charged colloid due to adsorption of I- from dispersion medium
41
Colloidal Sol formed when KI solution is added to AgNO3 solution is
AgI/Ag+ positively charged due to adsorption of Ag+ from dispersion medium
42
FeCl3 added to excess hot water SOl formed is
Fe2O3 xH2O/Fe3+ positively charged Sol
43
FeCl3 added to NaOH sol formed is
Fe2O3.xH2O/OH- negatively charged sol
44
colloids form two layers of opposites charges known as -----------
Helmholtz electrical double layer
45
Potential difference due to Helmholtz electrical double layer is called
Zeta potential or electrokinetic potential
46
movement of colloid particles under applied electric potential is called
electrophoresis
47
prevention of movement of particles during electrophoresis leads to
electroosmosis movement of dispersion medium
48
boiling of colloidal sol leads to
coagulation
49
increasing order of power of coagulation of negative sol by Al3+, Ba2+and Na+
Al3+>Ba2+>Na+ flocculatiing power increases with charge
50
minimum concntration of electrolyte in Millimoles per lit to cause precipitation of sol in two hours is called
Coagulating value
51
coagulating value is lowest for PO4 3-, Cl-, SO4 2-
PO43- as charge is highest
52
factors responsible for stability of lyophillic sols
charge and solvation