metallurgy Flashcards
elements occurring in free state
carbon, gold sulfur and noble gases
most abundant metal
aluminun
ores of aluminum
bauxite, kaolinite
Haematite and Magnetite are
I
Fe2O3, Fe3O4
Siderite
FeCO3
Iron pyrites
FeS2
Copper pyrites
CuFeS2
Malachite
CuCO3.Cu(OH)2
Cuprite
Cu2O
Copper glance
Cu2S
Zinc blende or Sphalerite
ZnS
Calamine
ZnCO3
Zincite
ZnO
Froth Floatation Method used for —————- ores
sulfide
Depressant used to separate ZnS and PbS
NaCN
leaching of bauxite gives
Sodium aluminate
Al2O3 (s) + 2NaOH(aq) + 3H2O(l) → 2NaAl(OH)4
CO2 reaction with sodium aluminate after leaching gives
Hydrated Al2O3
2NaAl(OH)4 + CO2 (g) → Al2O3.xH2O(s) + 2NaHCO3 (aq)
silver and gold are leached with
NaCN or KCN
4M(s) + 8CN–(aq)+ 2H2O(aq) + O2(g) → 4[M(CN)2– (aq) +4OH–(aq) (M= Ag or Au)
calcination of ZnCO3 gives
ZnO
ZnCO3 (s) ——ZnO(s) + CO2 (g)
The sulphide ores of copper are roasted in
reverberatory furnace
‘flux’ is added which combines with ‘gangue’ to form
Slag
Copper matte consists of
Cu2S and FeS
SO2 produced in reverberatory furnace us used in
Preparation of H2SO4