Structure 2.2 Flashcards
When are covalent bonds formed?
When electrons from different atoms are shared so that each atom attains a noble gas electron configuration (full valence shell). Known as the octet rule.
Single covalent bond
When one pair of electrons is shared between two atoms
Double covalent bond
Two pairs of shared electrons
Triple covalent bonds
Three pairs of shared electrons
Bond strength ___ as bond length decreases, as the number of shared pairs of electrons ___
increases, increases
The greater the number of shared pairs of electrons, the ___ the attraction between the two covalently bonded atoms
greater
Coordination covalent bonds
Covalent bonds where both the shared electrons come from the same atom
Arrows in lewis diagrams signify…
coordination covalent bonds
What is an incomplete octet?
An exception to the octet rule where atoms are stable with fewer than 8 electrons in their valence shell. This usually happens with elements like boron (6val e) and beryllium (4val e).
Electron deficient
Electron deficient describes molecules or atoms that don’t have enough electrons to achieve a full octet around one or more atoms. These molecules often contain atoms like boron or beryllium, which are stable with fewer than 8 electrons.
Electronegativity
A relative measure of the attraction an atom has for a shared pair of electrons when it is covalently bonded to another atom
Trend in electronegativity values
They increase across a period and up a group. Most electronegative elements are F, O and N. H is similar to C
What is the polarity of a covalent bond between two atoms of the same element?
Non-polar as the bonding pair of electrons is shared equally between the two atoms
What results in a polar bond?
A covalent bond between two different types of atoms. The more electronegative atom will attract the bonding pair of electrons making that atom the negative dipole.
What happens if the difference in electronegativity between the two covalently bonded atoms is greater than 1.8?
The bonding pair of electrons moves completely towards the more electronegative atom and the bonding becomes ionic.