Structure 1.3 Flashcards
First ionisation energy
The energy required to remove one electron from an atom in the gaseous state
What is ionisation energy measured in?
kJ mol-1
Periodicity
A repeating pattern/ recurring trend of a property
Elements with the lowest first ionisation energies
Alkali metals (group one)
Elements with the highest first ionisation energies
Noble Gases (group 18)
What is evidence of the max no. of electrons in each main energy level and sub-level?
The patterns in a graph of the first ionisation energies for the first 86 elements repeating after 2 then 8 then 18 etc
Why is it easier to remove an electron from a new sub-level compared to a full sub-level?
It is easier to remove an electron from a new sub-level because the electron is less stable and more weakly held compared to a full sub-level, where the electrons are more stable due to the filled configuration.
Why does it require more energy to remove successive electrons from an ion?
Because the number of p+’s exceeds the number of remaining e-‘s, inc the attraction between the e-‘s and p+’s and dec the repulsion between e-‘s. This pulls the e- cloud closer to the nucleus and holds them tighter due to the inc electrostatic attraction. Once all valence e-‘s have been removed the energy required to remove the next e- inc sharply.
Transitioning up energy levels is an __thermic change
endo(thermic)
Transitioning down energy levels is an __thermic change
exo(thermic)