Structure 1.3 Flashcards

1
Q

First ionisation energy

A

The energy required to remove one electron from an atom in the gaseous state

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2
Q

What is ionisation energy measured in?

A

kJ mol-1

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3
Q

Periodicity

A

A repeating pattern/ recurring trend of a property

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4
Q

Elements with the lowest first ionisation energies

A

Alkali metals (group one)

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5
Q

Elements with the highest first ionisation energies

A

Noble Gases (group 18)

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6
Q

What is evidence of the max no. of electrons in each main energy level and sub-level?

A

The patterns in a graph of the first ionisation energies for the first 86 elements repeating after 2 then 8 then 18 etc

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7
Q

Why is it easier to remove an electron from a new sub-level compared to a full sub-level?

A

It is easier to remove an electron from a new sub-level because the electron is less stable and more weakly held compared to a full sub-level, where the electrons are more stable due to the filled configuration.

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8
Q

Why does it require more energy to remove successive electrons from an ion?

A

Because the number of p+’s exceeds the number of remaining e-‘s, inc the attraction between the e-‘s and p+’s and dec the repulsion between e-‘s. This pulls the e- cloud closer to the nucleus and holds them tighter due to the inc electrostatic attraction. Once all valence e-‘s have been removed the energy required to remove the next e- inc sharply.

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9
Q

Transitioning up energy levels is an __thermic change

A

endo(thermic)

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10
Q

Transitioning down energy levels is an __thermic change

A

exo(thermic)

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