Stoichiometry Flashcards

0
Q

What is an excess reagent?

A

The reagent that is present in larger quantities than necessary

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1
Q

What is a limiting reagent?

A

The reactant that determines how much product can be formed

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2
Q

What is predicted or theoretical yield?

A

The expected amount of product

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3
Q

What is experimental or actual yields?

A

The quantity of the product actually obtained

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4
Q

How likely is it for the predicted and experimental yields to be the same?

A

Extremely rare

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5
Q

How do you do calculations for limited and excess reagents?

A
  1. Calculate the moles of each reactant
  2. Divide the moles of that reactant by its coefficient
  3. The lower number is the limiting reagent
  4. Use this as moles given
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6
Q

What factors affect experimental yields?

A
  1. Competing reactions
  2. Reaction is very slow
  3. Collection and transfer methods
  4. Reactant or product purity
  5. Reaction doesn’t go to completion
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7
Q

What are competing reactions?

A

When two chemicals react to give different products

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8
Q

What is an ideal percent yield?

A

As close to 100% as possible

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9
Q

How is percent yield calculated?

A

%yield = (actual yield/predicted yield) x 100

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10
Q

When the percent error is closer to zero, is it better or worse?

A

Better

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11
Q

How do you calculate percent error?

A

%error=(actual-predicted)/predicted x 100

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12
Q

What is a titration?

A

A procedure used to find the volume of substances so you can calculate the concentration

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13
Q

What is standardization?

A

When a solution of known concentration, a standard solution, is reacted with a solution of unknown concentration

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14
Q

What types of chemicals need to be standardized and why?

A

Strong acids and strong bases because their concentrations will change over time

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15
Q

What is a titrant?

A

A solution that is transferred from a precisely marked tube called a burette to a flask containing the sample and an indicator

16
Q

Why is an indicator used?

A

Because a sudden change in color indicates the completion of the reaction

17
Q

What is the endpoint?

A

The point where the titrant reacts completely with the sample

18
Q

What is the equivalence point?

A

The volume needed to reach the endpoint

19
Q

What is a pH titration curve?

A

A plot of the pH versus the volume of titrant added

20
Q

How are titration curves shaped?

A

They are S-shaped

21
Q

What happens when a strong monoprotic acid is titrated with a strong monoprotic base?

A

The equivalence point will always have a pH of seven at 25°C

22
Q

What does the first point on the curve indicate?

A

The pH of the sample

23
Q

What is the buffer region

A

The pH changes very gradually at first

24
Q

What happens to the rate of change as the point is approached?

A

The pH changes very rapidly

25
Q

What is stoichiometry?

A

The study of the relative quantities of reactants and products in a chemical reaction

26
Q

How do you find the moles of a substance when given the moles of another substance in the chemical reaction

A

NW = NG x W/G

27
Q

What does gravimetric mean?

A

Mass measurements

28
Q

How do you find moles using mass and molar mass?

A

n = m/M

29
Q

When can you use the law of combining volumes?

A

When the pressure and temperature conditions are constant for both the reactants and products

30
Q

What is the ideal gas law?

A

PV = nRT