stochiometry (1.4-1.5) Flashcards

1
Q

whats the standard unit of amount of susbtance

A

the mole

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2
Q

what does the mole contain

A

exactly the number of elementary given by the avogrados constant (6.0 X 10ˆ23)

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3
Q

what are the mass of an atom compared to

A

carbon 12 and are expressed as relative atomic mass Ar and relative formula mass Mr

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4
Q

whats the empircal formula

A

simplest whole ratio of atoms of each element present in compound

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5
Q

whats molecular formula

A

ratio shows actual amount of atoms of each element present in that compound

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6
Q

how do you prepare a standard solution

A

-weigh weighing boat, note mass
-add about 2g acid, note mass
-add acid to washed beaker
-reqeigh the boat and wirte the weight
-add 50ml distileled water to beaker stir to dissolve crystals crush them-put a washed funne into washed volumetric flask and carefully pour the acid down stirring rod into funnel do not lose any acid
-return rod to beaker and add 50 ml to rinse beaker and add to flask rinse rod and funnel, do not go over 250ml
-put lid into flask secure base and shake

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7
Q

convert from cm cubed to dm cubed

A

cm-dm = /1000

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8
Q

how can you express conecntration

A

[ ] square brackets

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9
Q

describe how to carry out an acid based titration

A

-rinse buretter with small amount of acid, throw to waste
-fill burette with acid until bottom of miniscus 0.00 line
-rinse pipette with base/ alklai
-use pump and volumetric pipetter to pipette 25 ml of base into conical flask
-add a few drops of indicator eg.phenolpthalein indicator
-add acid washing and swirling until you achieve a pale pink color
-record volume on burette
-wash out flask and repeat
-achieve until you have 2 concordant results (within 0.2)

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10
Q

how do you calculate uncertaintys

A

divide the uncertainty of aparatus by weight or value of measured eg mass times by 100% and all uncertaintys, and calculate the percentage difference from og value

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11
Q

what does avogrados law state

A

equal volumes of all gases under same conditions (temp and pressure) contain euqal numbers of mlecules (22.7 dm cubed molˆ-1)

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12
Q

equation relating gases and moles

A

volume= mol * 22.7

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13
Q

whats the mr of a molecule

A

the sum of all the relative atomic masses

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14
Q

whats the Ar

A

atomic masses of the constituent elements in the molecule

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15
Q

what are the standar conditions

A

273K, 100KPa

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16
Q

what is an ideal gas

A

-moving particles with negible volume and intermoecular forces
-all collisions between particles are considered elastic and frictionless( no energy loss in motion or collision)
-moelcules constantly moving in random directions with distribution of speeds
-molecules of gas are indistinguishible small hard spheres that are point-like

17
Q

why are gases no ideal

A

-some factors such as gravity will cause particles to have variable concentrations
-particles have intermolecular forces attractive and electrons are repulsive

18
Q

what causes the attractive forces between the particles to be negiligible

A

great seperation of the particles

19
Q

what happens to pressure when volume is halved

A

doubles the collisions, doubles pressure

20
Q

what happens when double numb of moles to pressure

A

double the numb of collisions, doubles pressure

21
Q

what happens when double temp to pressure

A

double temp you double the KE and therefore double the collisions and the pressure

22
Q

describe graph of p against v

A

they are inversely porportional
when its p vs 1/v then its a positive correlation, directly porportional

23
Q

describe graph of v against T

A

directly porportional

24
Q

describe graph of T against P

A

directly porportional

25
what are characterisitcs good to be used as standard solutions
it has high relative molecular mass- reduces our uncertainty it is soluble- all dissolve it is stable in the atmosphere (non-hygroscopic and unreactive)- non-hygroscopis= does not absorb water from atmosphere unreactive
26
accuracy
all results are equal or close to true value, results which are inaccurate are because of random erros eg incorrect use of equipment, human errors
27
precise
very close to average, can be inaccurate because of systematic errors eg. un calibrated balance