stereochemistry Flashcards
stereochemistry
where the atoms are joined in the same order but they have a different arrangement in space
2 types of stereochemistry
geometric and optical
geometric isomers
occurs in molecules containing a C=C, no free rotation around the pi bond so atoms are fixed in space
cis and trans isomers
are different compounds and have different properties
optical isomers
when 4 different atoms are arranged around a single atom the molecule can exist in two isometric forms and these isomers are non superimposable mirror images of each other
chiral centre
a central carbon which has 4 different groups attached
optical isomer properties
identical both in their physical and chemical properties and they differ in the way they affect plane polarised light as one will rotate polarised light to the right and the other to the left
racemic mixture
mixtures which contain equal amounts of both optical isomers and the isomers rotate polarised light in opposite directions so are optically inactive