stereochemistry Flashcards

1
Q

stereochemistry

A

where the atoms are joined in the same order but they have a different arrangement in space

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

2 types of stereochemistry

A

geometric and optical

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

geometric isomers

A

occurs in molecules containing a C=C, no free rotation around the pi bond so atoms are fixed in space

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

cis and trans isomers

A

are different compounds and have different properties

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

optical isomers

A

when 4 different atoms are arranged around a single atom the molecule can exist in two isometric forms and these isomers are non superimposable mirror images of each other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

chiral centre

A

a central carbon which has 4 different groups attached

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

optical isomer properties

A

identical both in their physical and chemical properties and they differ in the way they affect plane polarised light as one will rotate polarised light to the right and the other to the left

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

racemic mixture

A

mixtures which contain equal amounts of both optical isomers and the isomers rotate polarised light in opposite directions so are optically inactive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly