SR Reactions of Nitrobenzene Flashcards

1
Q
Nitrobenzene => Phenylamine 
Equation
Type of reaction
Conditions 
Reagents
A
-Nitrobenzene + 6[H] => Phenylamine +H2O
Step 1. Nitro + [H] => phenylammonium salt
Step 2. Phenyl salt + excess NaOH => phenylamine + 2H20
Type of reaction
-Reduction reaction
Conditions 
-reflux, [H] (tin and concentrated HCl)
Reagents
-Tin/Con HCl
-excess NaOH

P

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2
Q
Nitrobenzene => Bromonitrobenzene
Equation
Type of reaction
Conditions 
Reagents
A
Equation
Nitrobenzene + Br2 => bromonitrobenzene + HBr
Type of reaction
Bromination 
Conditions 
*Reaction is v. Slow at rt because the benzene ring in nitrobenzene is less susceptible to e- attack than benzene. so Halogen carrier catalyst is needed
High temperature 
Reagents
Br2
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