Spectroscopy Flashcards

1
Q

wavenumber for C=O

A

1650-1750cm-1

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2
Q

cm-1 for nitrile

A

2200cm-1

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3
Q

cm-1 for N-H

A

3200-3500 one sharp peak

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4
Q

NH2 cm-1

A

3200-3500 two sharp peaks

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5
Q

C-H cm-1

A

big pointy peaks around 3000cm-1

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6
Q

NO2 cm-1

A

vampire teeth peaks at 1300-1400 and 1500-1600

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7
Q

OH cm-1

A

3200-3300 broad peak

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8
Q

COOH cm-1

A

on top of 3000cm-1

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9
Q

Purpose of IR spectroscopy

A

identify functional groups (NOTE: if O or N is present)

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10
Q

CNMR for aldehydes and ketons

A

> 200 ppm

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11
Q

CNMR for esters, cacid, and amides

A

160-180ppm

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12
Q

TMS

A

0ppm

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13
Q

HNMR for benzylic

A

6-8 ppm

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14
Q

HNMR for aldehyde and phenol

A

10 ppm

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15
Q

HNMR c-acid and amide H’s

A

12-14

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16
Q

HNMR for double bond land - sp2

A

4-6

17
Q

HNMR alcohol and amine H

A

0.5-5.5

18
Q

HNMR single bond sp3

A

1-5

19
Q

When consider CNMR?

A

when compound has C=O in it

20
Q

What to focus on for HNMR

A
  • integral numbers
  • peak locations
  • splitting
21
Q

What is UV-VIS spectro used for?

A

analyze compound with conjug bonds

22
Q

What is mass spectrometry for?

A

determine compounds mass/fragmentation/formula

23
Q

Equation for degrees of unsaturation

A

C - (H/2) - (N/2) - (X/2) + 1