Solvents Flashcards

0
Q

What are the flash point ranges for class I, II and III liquids?

A

This standard is obsolete. Two agencies that still have a class III are:
DOT Flash point between 141° F and 200° F
(Combustible liquid) - Class III
United Nations (UN) flash points
Up to 141° F - Class 3.3
0° F to 73° F - Class 2
Below 0° F - Class 1

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1
Q

What is the flash point range for combustible liquids?

A
OSHA Combustible - 100° F to 200° F
Dot Combustible - 141° F to 200° F
(Also FYI)
OSHA Flammable - less than 100° F
DOT and IATA Flammable - up to 141° F
RCRA Ignitable - less than 141° F
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2
Q

What is perc (or perchloroethylene)?

A

A chlorinated solvent formally used in dry cleaning. It is being replaced by petroleum solvents due to environmental concerns.

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3
Q

Name one solvent in each of the following categories: Petroleum solvents, “coal tar” solvents, chlorinated solvents, oxygenated solvents.

A

Petroleum solvents-mineral spirits, Stoddard solvent
Coal tar solvents-toluene, xylene (which are also considered petroleum solvents)
Chlorinated solvents-trichloroethylene, perchloroethylene
Oxygenated solvents-MEK, acetone

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4
Q

What is a TLV?

A

Threshold limit value (TLV) - the maximum concentration that may be inhailed over and 8-hour work day, 40-hour work week with minimal hazard to health.

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5
Q

Name three common methods of industrial cleaning.

A

Alkaline cleaners
“Cold” cleaning with chlorinated and hydrocarbon solvents
Vapor degreasing

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6
Q

What property does aniline point and Kauri Butanol test?

A

Solvency

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7
Q

What are some important solvent properties?

A
Solvency
As measured by aniline point and/or Kauri Butanol value
Distillation range
Flash point
Evaporation rate
Regulatory compliance
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8
Q

What is a VOC?

A

Volatile Organic Compound

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9
Q

Does a solvent with a mixed aniline point of around 500° F have relatively high or low solvency?

A

Relatively high solvency

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10
Q

What is the difference between an aromatic and aliphatic solvent?

A

Aromatics contain a benzene ring as part of their molecular structure. They have high odor, solvency and toxicity. Aliphatics do not contain benzene rings. They have lower odor, solvency and toxicity.

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11
Q

Organic solvents can come from ________ _______ or _______ ______.

A

Crude oil or coal tar

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12
Q

A surfactant is defined as a ____________________________ __________________________________________________.

A

A surface-active agent that reduces the interfacial tension of a liquid.

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13
Q

Organic solvents used for maintenance cleaning can be classified as _________, __________, and ____________.

A

Petroleum
Oxygenated
Halogenated

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14
Q

How do toxic materials enter the body?

A

Ingestion
Respiration
Through the skin
Through the eyes

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15
Q

Name three components of the “fire triangle”, or, what three things are necessary for combustion to occur?

A

Oxygen
Fuel
Ignition Source

16
Q

Why are VOC’s being phased out?

A

Regulations limiting Volatile Organic Compounds address concerns about pollution and global warming.

17
Q

What is the fastest growing type of maintenance cleaning?

A

Water based cleaners to replace petroleum or halogenated cleaners.

18
Q

How should you dispose of spent (used) cleaning solvents?

A

In an environmentally responsible manner.

19
Q

Name two solvents that are potential depleters of the ozone layer under the international Montreal protocol.

A

1,1,1-trichloroethane
Halons
Chlorofluorocarbons
Carbon tetrachloride

20
Q

What things need to be considered when selecting a solvent ? List five.

A
What you want to clean
Hygiene requirements 
Disposal requirements 
Safe use of the solvent 
Solubility of material in the solvent
21
Q

Carbon tetrachloride, 1,1,1-trichloroethane, chlorofluorocarbons are all what types of solvents?

A

Chlorinated Solvents

22
Q

What physical characteristic make all three solvents (1,1,1-trichloroethane, carbon tetrachloride, and chlorofluorocarbons) attractive for plant use as solvents?

A

Non Flammable

23
Q

What does the “Minimum Ignition Temperature” (MIT) mean for a solvent?

A

The ignition source has to be at or above the MIT (Minimum Ignition Temperature) before there is ignition of vapor/air mixture.

24
Q

Besides time, name three things that can be done to improve solvent cleaning.

A

Increase temperature
Increase agitation
Use a solvent with greater solvency

25
Q

What are some criteria to consider when selecting a solvent-type cleaner?

A
Type of soil
Degree of cleanliness required
Health and fire hazard potential
Equipment required
Environmental
Safety and health regulations
Resistance of materials to solvent attack