solutions Flashcards

1
Q

solutions

A

homogeneous mixture of two or more substances
homogeneous molecular dispertion of two of more that two substances the relative properties of whcich may vary between certain limits

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2
Q

componenets

A

solute and solvent

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3
Q

classification of solution

A

-on the basis of size of dispersed phase
-on the bases of route of administration
-on the bases of composition and use
-on the basis of vehicle and solvent
-on he basis of physical state of solute and solvent

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4
Q

on the basis of size of dispersed phase

A

there categories-
1- true solutions: small molecules/ions, particles size is less than 1 x10-6 mm ex) sugar solution
2- collidal solutions: single lare molecules/ion, particle size is from 10-6-10-3mm ex) milk, blood
3- coarse solution: aggreate molecule or ions, particle size is less 1 x 10-3 mm ex) suspenions, emulsions

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5
Q

on the basis of root of administration

A

oral solutions- a medicine in liuid form for drinking (simple syrup BP or USP)

otic solution- those solutions which are instilled into the ear (oflaxcin otic solution, ciprofloacin and dexamethasane)

opthalamic solution- solutions which are instilled into eyes (tobramycin- treat eye infections, lifitgrastt- dry eye syndrome)

topical solutions- applied on skin (aluminium acetate)

prentaral solutions- olutions, suspentions, emulsions for injections or infusions, powders, gels (calcium soln, dextrose, electrolyte solutions.o

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6
Q

on the basis of vehicle and solvent

A

-aqeous solutions: these solutions which have water as the solvents (sugar and water, carbon dioxide in water, NaCl in water)

-non-aqeous solutions- these solutions having a solvent that is not water. it could be benzene ether, petrol, carbon, tetrachloride, (sulfur in cabon disulphide)

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7
Q

on the basis of composition and use

A

syrup- are sweetened, concentrated, aqeous solutions, concentrated solution of sugar and sugar sunstitutes, with or without medicated agents

elixir- pleasently flavoured sweetened hydroalcoholic preparations intended for oral use (3- 70%)

spirit- more than 90%% alcohol

tinctures- hydroalcoholic preparations obtained from natural source or synthesized

injections- a way of administrating a liquid to a person using a needel and syringe

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8
Q

on the basis of physical state of solvent

A

gas-gase= Air
liquid-gas water in oxygen
solid-gas= iodine vapours in smoke
gas-liquid= carbonated water
liquid-liquid= emulsion/alcohol in water
solid-liquid= NaCL in water
gas-solid= hydrogen on pladium
liquid-solid= amalgan(mercury in gold)
solid-solid alloys (copper and tin)

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9
Q

non-electrolytes

A

cannot be dissacociated into ions
bad conductirs of electricity
glyerin, urea, sucrose

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10
Q

electrolytes

A

-which are going to be dissoiated into ions
-good conductors of electricity
-strong elctrolytes (completely dissacociated- HCL)
-weak electrolytes (do not dissacociate completly- ephedrine)

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11
Q

concentration expressions

A

concentration of solute- amount of solute dissolved in given amount of solvent
the soution concentration can be expressed in:
-percentage expression
-molarity
-molality
-normaliy
-mole fraction
-PPM/PPB

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12
Q

percentage expression

A

parts of solute in total parts of solutions is equal to 100. ways to calculate:

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13
Q

molarit

A

no of moles of solute dissolved in 1L solution denoted by ‘M”, mathematically

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14
Q

molality

A

no of moles of solute dissolved in 1kg of solvent, denoted by ‘m’. mathematically,

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15
Q

nomality

A

no of gram equivalent of solute in 1L of solution, denoted by ‘N’

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16
Q

mole fraction

A

no of moles of a component divided by total number of moles of all the components present in a solution denoted by ‘X’.

17
Q

PPM

A

no of parts (by wt or V) of a solute per million parts (by wt or V) of solution

18
Q

PPB

A

no of parts (by wt or V) of a solute per billion parts (by wt or V) of solution

19
Q

ideal and real solution

A

ideal solutions are those solutions which obey raoult’s law. real solutions do not obey raoults law

20
Q

vapour pressure

A

the pressure exerted by the vapour exerted on the surface of liquid/solution

21
Q

factos affecting Vp

A

-temperature is directly propotional to Vp
-nature of liquid weaker intermolecular forces the more is the vapour pressure and vie versa
-boiling point is inversly propertional to vP
-purity of liquid

22
Q

raoults law

A

-1887, by french chemist francols. marie raoult
-it is skated as “for any volatile substance, the partial pressue exerted by the vapours/gas on the surface of liquid/gas solution is directly proportional to its nole fraction in liquid/gas
-