Adsorption Flashcards
adsorption
adsorption is a surface proces that leads to transfer of a molecule from fluid bulk to a olid surface. This can occur because physical forces or by chemical bondes
or
adsroption is the adhesion, of atoms ions, or molecules froma gas liquid, or dissolved solid to a surface
ex) painting on walls, water droplets on window
adsorbate
subtances which is deposited on the surface of another substance
Ex) H2, N2, O2
adsrobent
surface of the substace on which adorbent adsorbs
ex) charcoal, silica gel, alumina
physical adsorption
also known as physisorption. it is due to weak van der waal forces betweena adrobate and adsrobent.
Ex) H2, or N2, adsorbs on charcoal
chemical adsorption
also known as chemimisorption. it is due to strong chemical forces of bonding type between adsorbate and adsrobent. we can take the example involving the formation iron nitride on the surface when iron is heated. adsorption on gas on a solid is a spontaneous exothermic reaction
characteristics of physical adsorption
-surface area, temp, pressue, nature of adsorbate affects PA
-energy for activation is low (20-40Kj/mole)
-this type of adsorption is caused by physical forces
-physisorption is a weak phenomenon
-this type of adsorption is almost a multi-layered phernomenon
-it is reversible
characterstics of chemical adsorption
-surface area, temperaure, nature of adorbate effect chemisorption
-energy of activation is very high 40-400KJ/mole
-it is very strong process
-thi type of adsorption is almost a single layered phenomenon
-it is irreversible
factors affecting extent of adsorption
-nature of adsorbent
-surface area
-nature of gase
-exothermic nature
-pressue
nature of adsorbent
the adsorption of the gas depends on the nature of the adsorbent. A gas can be adsorbed on different adsorbent surfaces in different amounts
surface area
when we increase the surface area of the adsobent there is an increase in the adsrption of gases. This is because when we increase the surface area there is more number of adsorbing sites. so finely divided solid and some porous substances are good substances
nature of the gas
in general, it a gas is more liquifiable it will be more easily adsorbed. For examples gases like NH3, HCL, Cl2, CO2, which can be liquified easily are more readily adsorbed on the solids surface rather than permanent gases like O2, H2, etc.
exothermic nature
the heat of adsorption can be defined as the energy liberated when 1g mole of gas is adsorbed on a solid surace. Doing the process of adsorption adsorbent surface forms bonds with adsorbate molecules which increases stability abd releases energy
pressure
on the solid surface, there is a fixed number of adsorption sites where gas molecules can be adsorbed. Initially when the pressure has increases the rate of adsorption increases due to increase in the gas molecules striking on the surface, Thus an increase in the pressure increases the rate of adsorption linearly
applications of adsorption
-air pollution masks
-purification of water/softening hard ward
-removal of moisture and humidity
-in preserving vacuum
-in paint industry
-in dyeing
-recovery of chemical from industrial gases
application of adsorption in pharmacy
adsorption of small drug particles on the surface of large excipients has been widely used in the pharmaceutical industry for various purposues, such as improving content uniformly of low-dose drugs, enhancing the dissolution rate for poorly water-soluble drug. used in chromotography technuques for the separation of organic substances