Solutions Flashcards
What does slightly soluble mean
low temps it doesn’t dissolve but at higher temps it dissolves a little
Unsaturated solution
More solute can be added and it will still dissolve
Saturated solution
when no more solute can dissolve, solvent and solute are in equal amounts, if more solute is added a solid precipitate will form
Supersaturated solution
increasing the temp or pressure which then allows more solute to dissolve, then decreasing the temp it becomes supersaturated
Solubility
Measured as grams of solute per 100g of solvent
Solubility affecting factors when a solid solute is added
Increasing temp, increases solubility (several exceptions) as average kinetic energy increases meaning particles have enough energy to overcome the forces of attraction in the solute and solvent allowing new interactions to occur, Decreasing particle size, increases solubility
Increasing stirring (speeding up particles), increases solubility
Solubility affecting factors in a gas solute
Increasing temp, decreases solubility as this increases the average kinetic energy which allows the molecules to break the intermolecular bonds escaping from the liquid, Increasing pressure, increases solubility
What must happen for a solution to form
Solute interaction forces need to be overcome for it to dissolve, Solvent interaction forces need to be overcome to make space for solute particles, New interactions must have greater or equal strength than that of solute-solute of solvent-solvent interactions
What do the particles have to do to form new interactions with greater energy
Particles must have correct orientation which occurs through Brownian motion (the erratic and random movement of molecules)
When does an ion-dipole interaction occur
When an ionic compound dissolves in water
What is an example of an ion-dipole interaction
When NaCl is dissolved in water the ion-dipole attractions between Na ions and Cl ions and the water molecules are strong enough to pull the ions from their positions in the crystal lattice
Hydration
When the water molecules surround the ions in a solution
What polar covalent molecules will ionise
Highly polar compounds will form ions when dissolved in water as the covalent bonds break when the compound is placed in water as a result of the electrostatic force of attraction between the solute molecules and water molecules
Polar covalent molecules that don’t ionise
Some polar covalent molecules don’t break down into ions and instead dissolves the attraction between the polar covalent molecules and polar water molecules which causes the covalent crystal structure to break up