Soil pH Flashcards
what does pH stand for?
Hydrogen power (pouvoir hydrogène) it's a logarithmic scale, so each pH measure multiplies the acidity/alkalinity by 10
What is pH?
A measure of a soils acidity or alkalinity by indicating the concentration of H+ on a scale
ex.
pH 5 is acidic
pH 8 is basic
What is a buffering capacity?
A soil’s ability to maintain its pH when changes are being made to the soil
T or F: High CEC = high buffering capacity? why/why not?
TRUE bc of the multiple exchange sites
What is a typical soil pH?
between 4 and 10
What pH do most crops prefer?
5.5-8.5? but really I think it’s 6.5-7.5 (neutral) double check
Which plant nutrient’s availability is the most pH dependent?
pHospHorous!
T or F: in very acidic soils, all nutrients are deficient except Fe, Mn, and Z and they can be toxic in their concentration
TRUE
T or F: some nutrients like Fe, Al, and Mn can become toxic to some plants in high concentrations
TRUE
T or F: fungi tend to be less tolerant to acidity
FALSE, fungi tend to be MORE tolerant to acidic soils (think about coniferous forests = very acidic)
what are Acidophiles? and can be found where? What do they do in these places?
organisms that can live at low pHs
can be found in sulphur pools, geysers, and mine drainage
they oxidize reduced sulphur into sulphuric acid
What are alkaliphiles? where do they live? what do they do?
organisms that can live at very high pHs - very few
found in highly basic conditions like soda lakes and high carbonate soils
can be distinguished into 2 groups - alkaliphiles and haloalkaliphiles (salt)
T or F: bacteria and actinomycetes are more tolerant of acidic conditions than fungi?
FALSE - fungi is more tolerant of acidity than bacteria and actinomycetes
T or F: fungi can grow at pH 3?
TRUE
What are calcareous soils? What happens to them when ___ gets into the soil particles?
Do they have a high or low pH?
Sodium rich soils
When sodium gets into the soil particles, they explode and can create cut outs and deep gorges
High pH
What are the acidic cations (2) and which are the basic (5) cations?
Acidic:
Hydrogen + Aluminum
Basic: Calcium Magnesium Sodium Potassium Ammonium
When do soils become acidic?
When cation exchange occurs and H+ is added to the solution and exchanges with non-acid ions (Ca, Mg, K, Na) held onto humus and clay colloids and then the non-acids can be easily leached with the soil solution, leaving behind an H+ dominated soil.
What are the 3 pools of acidity? Describe them
- Residual/reserve Acidity:
- the H+ and Al3+ ions that are BOUND (non-exchangeable) on soil particles - Exchangeable/ Adsorbed Acidity:
- H+ and Al3+ ions that are EASILY exchanged by other cations in the soil solution
- pH will change - Active Acidity:
- the H+ and Al3+ ions IN the soil SOLUTION
To measure pH, which pools of acidity do we look at?
soil solution NOT the reserve
Why can it be difficult to alter the pH of a clay soil? Which pools of acidity must be considered to change the pH?
Because the reserve acidity pool will continue to send out H+ or Al3+ ions to the rest of the soil to maintain the acidic pH - must apply enough lime to counter that and then actually neutralize the pH in the other pools = BUFFERING CAPACITY
both the residual and exchangeable pools must be considered
If you wanted to change the pH of a sandy soil, which pool of acid would not be as important to consider?
The reserve pool, you would just need to change the acidity of the solution - active!
LOW BUFFERING CAPACITY
What is the difference between the reserve and active acidity pools?
Active: the H+ ions IN THE SOLUTION
Reserve: is the H and Al ions that are absorbed
What are the different methods of measuring pH? which is the best and why?
- Field probe (what we used in class) = the best because it is the most accurate; relatively inexpensive; can take it right out into the field; very clear
- Colour strips: great for a backyard test to know whether soil is acidic or basic, but doesn’t tell you the actual pH - inaccurate; could be confused/dirtied/or lost in the field
What are the 5 inherent factors affecting pH?
ClORPT!
- Climate: rainfall, temperature, weathering - effect leaching rates, erosion/weathering
- Parent material: mineral content effects soil texture
- organisms: vegetation
- relief: slope, etc.
- time: the longer the action, the more time there is to change pH
Why do warm, humid, and high rainfall climates have lower pH soils?
Increased acidification is due to the high leaching rates from the high rainfall
Why does leaching increase pH?
it removes the basic ions that are replaced
How does a dry environment effect pH? Why?
where weathering and leaching are less intense, soils can have a high pH or be neutral because base cations are able to accumulate in the soil rather than be leached out or eroded and OH- ions can offset H+ ions
T or F: Temperate coastal climates contribute to lower pHs? why?
TRUE bc of the higher rainfall levels
ppt = more evaporation and leaching = more H+ ions in soil and less base ions
What are 7 causes of acidity?
- Rain (carbonic acid)
- biological activity
- accumulation of OM
- nitrification
- Acid rain (industry)
- plant uptake of cations and release of H+ (especially when plants are harvested, base ions are removed from the soil instead of being put back in when the plant dies)
- Industrial fertilizers
What are 4 problems with acidic soils?
- Al, Mn, Fe can become toxic to plants
- reduced microbial activity
- deficiency of other essential plant nutrients (Mg, Ca, Molybdenum)
- slow OM decomposition - deficiency in N, P, S
What are 8 ways a pH level that is too high or too low can effect soil function?
- nutrient deficiencies from leaching
- decline in microbial activity
- decrease in crop yields
- deterioration of overall soil health
- inhabitation of the N cycle
- limited effectiveness of herbicide and insecticides
- limited solubility of heavy metals
- a lack of effectiveness of herbicides
What are 4 ways acidification be limited or corrected?
- adding lime to increase pH
- adding N or S in the correct amounts and at the right times can be beneficial for plants
- diversifying crop rotations
- OM application increases the buffering capacity for pH changes