Shapes Of Molecules Flashcards
Why do differing shapes form
Bonds repel each other equally- and electrons in bonds want to be as far apart as possible
- maximum separation + minimum repulsion
How much more does a lone pair repel than a bonding pair
- generally each lone pair pushes the angle an extra 2.5•
- A structure just made of bonding pairs the angles will be equal
Name of structure and angle with 2BP
Linear
180•
Name of structure and angle with 3BP
Trigonal planar
120•
Name of structure and angle with 4BP
Tetrahedral
109.5•
Name of structure and angle with 5 BP
Trigonal Bipyramidial
120• between those on same plane
90• between those on different plane
Name of structure and angle with 6 BP
Octahedral
90•
Why do structures with no lone pairs have equal angles
Equal repulsion between bonding pairs = regular structures
Name of structure and angle 3BP and 1 LP
Trigonal pyramidal
107•
Name of structure and angle 2BP and 2LP
Bent / V-Shaped
104.5•
Name of structure and angle 3BP and 2LP
Distorted T
87.5•
Make of structure and angle 4BP and 1LP
Seesaw
87•
102•
Name of structure and angle 5BP and 1LP
Square pyramidal
90• between 4 on same plan
81.9 between those on same plane and top BP
Name of structure and angle 4BP
2LP
Square planar
90•
Lone pair on each side repel equally
Why do Lone pairs repel more than Bonding pairs
Lone pairs are held closer to the nucleus of an atom = Repel more