Shapes of molecules Flashcards
Electron pair repulsion theory
- Electron pairs around the central atom repel each other as far apart as possible
- The greater the number of electron pairs, the smaller the bond angle
- Lone pairs of electrons repel more strongly than bonded pairs of electrons
Linear
180, 2 bonded pairs with no lone pairs
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Trigonal planar
120 , three bonded pairs of electrons with no lone pairs
Tetrahedral
109.4 , 4 bonded pairs of electrons with no lone pairs
Octahedral
90 , 6 bonding pairs of electrons
Non-linear
2 bonding pairs lone p,airs
Pyramidal
107 , 3 bonding pairs with one lone pair
Electronegativity
A measure of attraction of a bonded atom for the pair of electrons in a covalent bond
Non polar bond
The bonded electron pair is shared equally between the bonded atoms
Polar bond
The bonded electron electron pair is shared unequally between the bonded atoms
permanent dipole-dipole
Polar molecules have permanent dipoles, will always have a negatively and positively charged end, they are attracted to each other.
London forces
Polar molecules have permanent dipoles, will always have a negatively and positively charged end, they are attracted to each other.