Periodicity Flashcards
First ionisation energy
is the energy needed to remove one mole of electrons from one mole of atoms from their gaseous state
Second ionisation
Is the energy required to remove one electron from each ion in one mole of gaseous 1+ ions of an element to from one mole of gaseous 2+ ions .
Three factors affecting the ionisation energy
- Atomic radius
- Nuclear charge
- Electron shielding
How does the atomic radius affect the ionisation
Atomic radius increases the attraction between the nucleus and outer electrons decreases
How does the nuclear charge affect ionisation
As the number of protons increases the attraction between the nucleus and outer electrons also increases
How does electron shielding affect ionisation
As the number of inner shells increase the attraction between the nucleus and the outer electrons decrease
What happens if there’s pairs in a sub level?
The paired electrons repel/push other electrons away making it easier to remove, decreasing the ionisation energy.
What happens to ionisation energy across a period?
The nuclear charge increases across the group, so there is a greater attraction between the nucleus and outer electrons so Ionisation energy would increase.
What is outweighed with first ionisation energies down a group?
Although nuclear charge increases its effect is outweighed by the increased radius and to a lesser extent, the increased shielding.
What happens to ionisation energy as you go up a group?
The ionisation energy increases - closer to nucleus, less shielding