Separation of The Basic Constituents Into groups Flashcards
What is the group no of Silver?
I
What is the group name and no. of Ag^+, Pb^+2, Hg2^+2
Silver and I
HCl (2-3 M)
Silver (Ag^+, Pb^+2, Hg2^+2)
What is the group no of Hydrogen Sulfide?
II
Copper subgroup: Cu^2, Cd^+2, Bi^3, Hg^2
Tin Subgroup: Ag^+3, Sb^+3, Sn^+4
Hydrogen Sulfide and I
0.3 M H^+ and H2S (10% thioacetamide)
Hydrogen Sulfide
What is the group no of Ammonium Sulfide?
III
Aluminum subgroup:
Al+3, Cr+3, Zn+2
Nickel subgroup: Fe+2, Fe+3,Mn+2, Ni+2, Co+2
III, Ammoniujm Sulfide
6 M NH4OH and H2S
or (NH4)2S (10%thioacetamide)
III Ammonium Sulfied
Group name of IV
Alkaline earth
Group member of Alkaline Earth
Ba+2, Sr+2, Ca+2, Mg+2
12 M NH4OH, 3M (NH4)2CO3 and 95%
EtOH
Precipitant of Alkaline earth IV
Group name of V
Alkali
Group member of Alkali
Na+, K+, Li+, NH4+
Precipitant of Alkali V
None
Cations of this group forms precipitates with dilute HCl
I-Silver Group
Ag+, Pb+2, Hg+2
I-Silver Group
Composed of metals that do not react with HCl.
II- Hydrogen Sulfide Group
They form ppt with H2S in dilute mineral acid.
II- Hydrogen Sulfide Group
sulfides of this subgroup
are insoluble in Na2S
Copper subgroup
sulfides of this subgroup are
soluble in Na2S
Tin subgroup
Cu+2, Cd+2, Bi+3, Hg+2
Copper Subgroup
Hg+2, As+3, Sb+3, Sn+2 ,Sn+4
Tin Subgroup
Copper Subgroup and Tin Subgroup is what group?
II-Hydrogen Sulfide Group
Example of II-Hydrogen Sulfide Group is
2Sb+3 + 3H2S → Sb2S3 (orange) + 6H
Example of I-Silver Group
Ag+ + Cl- → AgCl (white)
These cations do not react either with dilute HCl or
with H2S in dilute mineral acid medium.
III- Ammonium Sulfide Group
they are precipitated by H2S or (NH4)2S in ammoniacal solution.
III- Ammonium Sulfide Group
What is the 2 groups of III- Ammonium Sulfide Group?
Aluminum subgroup and Nickel Subgroup
sulfides and hydroxides
of this group are soluble in excess NaOH and
Na2O2 mixture
Aluminum Subgroup
Al+3, Cr+3, Zn+2
Aluminum Subgroup
sulfides and hydroxides of this
group are insoluble in excess NaOH and Na2O2 mixture
Nickel Subgroup
Fe+2, Fe+3, Mn+2, Ni+2, Co+2
Nickel Subgroup
Example of III-Ammonium Sulfide Group
Zn+2 + NH4OH → Zn(OH)2 (white)+ NH4+
These cations do not react with the precipitating agent of Group I-III.
IV- Alkaline Earth Group