Post Laboratory Discussion Flashcards
Describes how fast reactants are used up and products are formed
Rate of reaction
What will happen if is collisions among atoms, ions, molecules with sufficient energy and proper orientation
Chemical Reaction
What is the symbol for Activation Energy
Ea
Minimum amount of energy required to initiate a chemical reaction
Activation
Formula for activation energy
Ea = rate of rxn = t
Study of rates of chemical reactions, factors that affect reaction rates, and mechanisms by which reactions occure
Chemical kinetics
What are the factors that affect reaction rate?
Nature of reactants
Concentration
Temperature
Catalyst
Rate of rxns depends on the surface areas or degree of subdivision
Nature of reactants
Formula for nature of reactants
Smaller particles = rate
Rate of collisions = # number of collisions / s
Concentration
Average kinetic energy of molecules is proportional to the ____________
Temperature
Formula for temperature
T = KE = Collision of molecules
Are substances that can be added to reaction mixtures to increase the rate of reaction
Catalyst
The rate of a chemical reaction increases as the concentration ___________
Increases (DIRECTLY PROPORTIONAL)
Chemical rxns that occur in either direction
Reversible rxns
Exists when 2 opposing rxns occur simultaneously at the same rate
Chemical equilibrium
The system shifts in the direction that reduces the stress
Le Chatelier’s
3 types if changes that can disturb the equilibrium of a rxn
Changes in concentration
Changes in temperature
Changes in pressure or volume
What are directions where equilibrium shifts?
Left and Right
equation that includes the amount of heat in the chemical reaction either released (exothermic) or absorbed (endothermic)
Thermochemical Equation
Exothermic
Released
Endothermic
Absorbed
What is the Theory where it has the formula of PV = nRT
Ideal Gas Law
What is value of gas constant?
0.0821
__P = __V less # gas molecule =?
F
__P = __V greater # gas molecule =?
B
Hasten
Accelerator
Retard
Inhibitor
What does
- same moles
- inert gas
- (+) catalyst
have in common?
No effect in equilibrium
What is the color and conclusion of CH3COOH + Methyl Red?
Red and Acidic
What is the color and conclusion
CH3COOH + Methyl Red + NaCH3COO
Yellow and Basic
Chemical name of NaCH3COO
Sodium Acetate
What is conclusion of Reagents with Ion present is Co(H2O)6^+2 (hexaaquacobalt(2) complex ion)
Pink
What is conclusion of Reagents with Ion present is Co(H2O)6^+2 + HCl
Blue (CoCl4^-2) (tetrachlorocobaltate ion)
What is conclusion of Reagents with Ion present is Co(H2O)6^+2 + H20
Pink (Co(H2O)6^2)
What is conclusion of Reagents with Ion present is Co(H2O)6^+2 + AgNO3
Pink Soln + AgCl white precipitate
What is the Color and Nature of product of AgNO3 + HCl
AgCl + White precipitate
What is the Color and Nature of product of AgNO3 + HCl + HCl
More AgCl (increase Cl^-)
What is the Color and Nature of product of AgNO3 + HCl + NH4OH
Colorless solution Ag(NH3)2^+
What is the Color and Nature of product of AgNO3 + HCl + HCl
AgCl white precipitate (decrease Ag(NH3)2+)
What is the color of the reagents FeCl3 + KSCN
Old red soln
What is the color of the reagents FeCl3 + KSCN + Fe(NO3)3
Intensified red solution (inc Fe+3)
What is the color of the reagents FeCl3 + KSCN + KCl
Lightly red soln (inc KCl)
What is the color of the reagents FeCl3 + KSCN + Na2HPO4
Dissapearance of color (dec FeCl3) FePO4 white precipitate
What is the ionization of acetic acid?
Partially ionized
Why is acetic acid partially ionized?
because it is a weak acid
When NaCH3COO is added to CH3COO-, what happens to the ions?
It increases the CH3COO- ions in solution
When NaCH3COO is added to CH3COO-, what happens to the reaction?
backward rxn, decreasing the H+
hence becoming basic
AgCl (white) <–> Ag+ + Cl-, what happens if you add more HCl
It completes the reaction of AgCl thus it has a backward reaction
AgCl (white) <–> Ag+ + Cl-, What happens if NH4OH is added?
Decreases the Ag ions, thus it has a forward reactgion
AgCl (white) <–> Ag+ + Cl-, what happen if you added HCl with the Nh4OH,
Neutralizes the ammonia and increases Ag to precipitate again to AgCl
Fe+3 + SCN- <—-> Fe(SCN) +2, what happens if you added Fe(NO3)3
Increases the Fe+3 ions, thus it has a forward reaction
Fe+3 + SCN- → Fe(SCN) +2, what happens if you added KCl,
Decreases the Fe+3 ions forming FeCl3, Backward Reaction
Fe+3 + SCN- → Fe(SCN) +2, what happens if you added Na2HPO4
Decreases the Fe+3 ions forming FePO4, Backward Reaction