Separate Chemistry 2 - Ion tests Flashcards

1
Q

Which tests test for metal ions?

A
  • Flame test

- Hydroxide tests

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2
Q

What is the method for a flame test?

A

1) Clean the flame loop in acid
2) Place sample onto the loop
3) Place loop at the side of a roaring blue flame
4) Witness colour change

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3
Q

What are the results of different metals in a flame test?

A
Potassium (K+) --> Lilac flame
Lithium (Li+) --> Red flame
Sodium (Na+) --> Yellow flame
Calcium (Ca2+) --> Orange flame
Copper (Cu2+) --> Blue-green flame
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4
Q

How does a flame test work?

A

Excitation of outer electrons.

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5
Q

What is the method for a hydroxide test?

A

1) Dissolve the solid salt in distilled water
2) Add a few drops of sodium hydroxide
3) Record the colour of the precipitate

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6
Q

What are the results of different metals in a hydroxide test?

A
Iron II (Fe2+) --> Green
Iron III (Fe3+) --> Brown
Copper (Fe3+) --> Blue
Calcium (Ca2+) --> White
Aluminium (Al3+) --> White (dissolves with excess NaOH
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7
Q

How does the hydroxide test work?

A

Displacement reaction - sodium is more reactive and bonds to the hydroxide ions, leaving the metal precipitate.

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8
Q

What does the halide test, test for?

A

Halide ions.

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9
Q

Which tests test for non-metal ions?

A
  • Halide test
  • Carbonate test
  • Sulphate test
  • Ammonium test
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10
Q

What is the method for a halide test?

A

1) Dissolve the salt in distilled water
2) Add a few drops of nitric acid
3) Add a few drops of silver nitrate
4) Record the colour of the precipitate

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11
Q

What are the results of the different ions in a halide test?

A

Chloride (Cl-) –> White
Bromide (Br-) –> Cream
Iodine (I-) –> Yellow

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12
Q

How does a halide test work?

A

The silver reacts with the halide to form insoluble silver halides.

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13
Q

What is the method for a carbonate test?

A

1) Dissolve the solid in a few drops of acid
2) Observe for bubbles (gas production)
3) Bubble gas through limewater

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14
Q

What is the result of a carbonate test?

A

If carbon dioxide is being produced, the limewater will go cloudy.

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15
Q

What is the method for a sulphate test?

A

1) Dissolve the solid in distilled water
2) Add a few drops of hydrochloric acid
3) Add a few drops of barium chloride

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16
Q

What is the result of a sulphate test?

A

A white precipitate forms (insoluble barium sulphate).

17
Q

How does a sulphate test work?

A

The acid removes carbonate ions that might produce a false test.
Insoluble barium sulphate forms if sulphate is present.

18
Q

What is the method for an ammonium test?

A

1) Dissolve the solid salt in distilled water
2) Add sodium hydroxide and warm gently
3) Place damp red litmus paper in the test tube and observe

19
Q

What is the result of an ammonium test?

A

Red litmus paper will turn blue.

20
Q

What are three instrumental methods of detecting and analysing substances?

A
  • Mass spectrometry
  • Infrared spectroscopy
  • Gas chromatography
21
Q

How does mass spectrometry work?

A

It measures Mr values and identifies compounds.

22
Q

How does infrared spectroscopy work?

A

It detects covalent bonds and identifies compounds

23
Q

How does gas chromatography work?

A

It measures the amounts of each component in a mixture.

24
Q

What do instrumental tests offer?

A

Improved:

  • Sensitivity
  • Accuracy
  • Speed