Seminar 7: Intro to Energy Flashcards
first law of thermodynamics?
energy cannot be created/destroyed only transferred/transformed
second law of thermodynamics?
energy transformations increase the entropy (disorder) of the universe
different forms of energy & e.x
- chemical: bond energy
- heat:
- light:
4: kinetic: - electrical:
what are the 2 classifications of energy
kinetic & potential
what is the diff b/w kinetic & potential energy?
- kinetic is energy of movement, it does work, makes things (heat, light)
- potential is energy of state/position, it is stored (chemical, electrical)
why is ATP an energy rich molecule
- the terminal phosphates are both -ve & therefore repel each other greatly
- thus a lot of energy is required to form the bond b/w them
- when ATP is hydrolysed, the breakage of the terminal bond releases A LOT of energy
Describe the ATP cycle: How is ATP used and regenerated in a cell?
- free energy released from the hydrolysis of ATP may drive reactions through the transfer of a phosphate group to a reactant molecule
- this forms a more reactive phosphorylated intermediate
- ATP hydrolysis also powers the mechanical & transport work of a cell, often powering shape changes in the relevant motor proteins
- Cellular respiration, the catabolic breakdown of glucose, provides the energy for the endergonic regeneration of ATP from ADP & Pi.
How does ATP typically transfer energy from an exergonic to an endergonic reaction in the cell?
ATP usually transfers energy to an endergonic process by phosphorylating another molecule. (Exergonic process, in turn, phosphorylate ADP to regenerate ATP).
what are exergonic & endogonic reactions?
- exergonic releases energy (catabolic, cellular respiration)
- endogenic consumes energy (anabolic, photosynthesis, active transport)
differentiate b/w spontaneous & non spontaneous reactions
spontaneous occur w/o any energy input, non-spontaneous don’t
meaning of delta G values
delta G = free energy of products - free energy of reactants
-ve delta G = free energy released in reaction (exergonic)
+ve delta G = free energy required for reaction (endogenic)
what does delta G tell us abt a system?
stability
- more free energy (-ve) = less stable & greater work capacity
- less free energy (+ve) = more stable & less work capacity