Semiconductor Materials and Devices Flashcards
Give two expressions for the classical kinetic energy of a particle.
Check
Give the equations for angular frequency and wavevector.
Check
Give the expression for quantum mechanical KE of a free electron.
Check
State the TISE.
Check
Solve the TISE for a free election gas in volume L^3 stating an expression for the quantised energy states.
Check
State the Bragg reflection condition for electrons incident on crystal planes
n lambda = 2dsin(theta)
How can the Bragg condition be used to define the Brillion zone boundary?
If an electron travels normal to the plane, the Bragg reflection condition occurs when k=nπ/d. This means the electron wave vector will constantly be reflected back and forth (standing wave).
What is the state of the electron energy in a system when the standing waves of electron density has high density overlapping positive ion cores?
Low energy state.
What is the state of the electron energy in a system when the standing waves of electron density has high density between positive ion cores?
High energy state
What is the band gap at the Brillouin zone boundary?
For the same k vector, the electron states have different energies. The difference in these energies is the band gap.
Sketch the extended zone scheme and the reduced zone scheme band structure for electrons in the nearly free electron model.
Check slide 7
Why do energy gaps form at the Brillouin zone boundary in the NFE band structure?
The periodic potential of the crystal lattice causes energy gaps to appear in the FE model.
Define the 1st BZ in terms of reciprocal lattice vectors.
The 1st BZ is a closed volume about the origin in reciprocal space formed by bisecting near neighbour reciprocal lattice vectors.
Sketch band structures for the free electron, NFE, tight binding and free atom with energy on the y axis.
Check slide 9
Derive an expression for density of states.
Check slide 10
Define density of states.
The number of states with an energy between E and E+dE per unit volume.
What is true of the density of states at T=0K
The states are fully occupied up to the Fermi energy, Ef
What distribution defines the occupation of the density of states?
The Fermi-Dirac distribution function.
State the Fermi-Dirac distribution
Check
State how filled the bands are in a metal.
Electron density is such that the highest occupied band is partially filled.
State how filled the bands are in a semiconductor.
Highest band is completely filled at low T and the difference in energy to the next band is relatively small.
State how filled the bands are in an insulator.
Highest occupied band is completely filled at low T and the difference in energy to the next band is large.
What does conduction require?
A net electron momentum - changing the average k values. This causes a shift of the Fermi surface in k-space.
Why can’t insulators conduct (momentum)?
There are no empty states for the electrons to move into hence the electrons can gain no net momentum.
Each Brillouin zone contains how many electrons?
2 electrons per primitive unit cell in real space.
Atoms with odd numbers of electrons form what types of materials?
Metals.
Atoms with even numbers of electrons for what type of materials?
They may form semiconductors or insulators. This depends of the band overlap since directionality must be included
Can there be an energy discontinuity at each Brillouin zone but be no overall bandgap?
Yes it is possible. Check slide 19
Give the bandgaps in Si, GaAs and GaN
- 1 eV
- 4 eV
- 4 eV
What structure does GaAs have?
A zincblende cubic structure.
Define group velocity.
The group velocity of a wave is the velocity with which the variations in the shape of the wave’s amplitude (envelope) propagate through space.
Give an expression for group velocity.
Check
Give an expression for effective mass of an electron.
Check
When do electrons respond as if they have an effective momentum and an effective mass?
Inside a crystal electrons respond to outer forces as if they have an effective momentum hk (where k is the position of the electron along the band) and near the band edges they respond as if they have an effective mass m*.
For N free carrier of charge e, find the effective number of free electrons when an electric field of E is applied to the crystal.
Check slide 27
What is the effective number of electrons for a completely full band and when is the effective number of electrons at its maximum?
For a completely full band, the effective number of electrons is 0.
The effective number of electrons is at its maximum when the band is half full (metals).
What is a hole?
An empty state in the valence band.
How do holes behave differently to electrons?
The holes move in the direction of the electric field, thus they behave as if they are positively charged.
What is removing an electron with a negative effective mass from a full band equivalent to?
Introducing a single +ve charged particle of +ve mass.
Why is the effective mass of an electron in the valence band -ve?
The curvature at the top of the valence band is negative therefore electrons have a negative effective mass.
Why is the electron mass in the conduction band usually smaller than the hole mass in the valence band?
The curvature of the conduction band is usually greater.
What can be said about the positioning of a conduction band minimum?
It will always be at k=0 or at some point along symmetry directions.
Why can bands separate with split off energy ∆?
Bands can separate due to spin orbital coupling with split off energy ∆.
What kind of band gap does GaAs have?
Direct.
What kind of band gap does Si have?
Indirect
True or false, a direct band gap semiconductor such as GaAs has strong optical transmissions and can be used for light emission.
True
What is an intrinsic material?
A pure material where all carriers are thermally excited so the number of electrons (ni) is equal to the number of holes (pi)
Derive an expression for the concentration of electrons (n) in the conduction band of an intrinsic material at T, stating any approximations made.
Check slide 39-45
1) Use Boltzmann distribution for f(E)
2) integrate from E=Ec to E=∞ (ignoring finite width of conduction band)
State an expression for the hole concentration in the valence band of an intrinsic material.
Check
What are Nc and Nv and give expressions for them in terms of effective mass and h.
Nc is the effective density of states in the conduction band.
Nv is the effective density of states in the valence band.
Expressions can be checked on slide 45/6
State the law of mass action giving two expressions.
Check slide 46
Derive an expression for the position of the Fermi level in an intrinsic material.
Check slide 47
What is an extrinsic material?
A material that has been doped to increase carrier concentration.
What do donor atoms do in extrinsic materials?
Donate negative carriers making the material n-type.
What do acceptor atoms do in an extrinsic material?
Produce positive carriers making the material p-type
Why are small and medium band gap semiconductors easy to dope?
They produce shallow levels (close to the energy levels of the intrinsic material).
What happens when a group VI atom is added to a group III-V semiconductor (GaAs)?
The group VI dopant will go into the As sites so dope n-type.
What happens when a group II atom is added to a group III-V semiconductor (GaAs)?
The group II dopant will go into the Ga sites so dope p-type.
What happens when a group IV atom is added to a group III-V semiconductor (GaAs)?
The group IV dopant will go into the Ga sites so dope n-type.
What limits are there on dopant concentrations in extrinsic semiconductors?
The minimum carrier conc cannot be lower than the intrinsic carrier conc of the material.
The maximum carrier conc cannot be greater than the solubility of the dopant in the material.
In what materials are donor and acceptor atoms in?
Donors in n-type
Acceptors in p-type
When is Boltzmann statistics a good approximation to Fermi statistics?
When Ec-Ef ≥ 2kT
Find expressions for the position of the Fermi energy in an n or p doped material.
Check slide 61
What happens to the Fermi energy when a material is n-doped?
It tends towards the conduction energy.
What happens to the Fermi energy when a material is p-doped?
It tends towards the valence energy.
What is true in a neutral p-type material about the number of holes and acceptors?
They are equal.
What is true in a neutral n-type material about the number of electrons and donors?
They are equal.
What happens to the Fermi energy of an extrinsic material as temperature increases?
It tends towards the intrinsic Fermi energy.
Give an expression for the total KE of an electron considering it is free to wander in 3 dimensions.
Check slide 67
In a perfect periodic material, electrons suffer no scattering but in real materials, what can electrons be scattered by?
Lattice vibrations (phonons) Impurities, defects Electron-electron, electron-hole interactions
What is the motion of carriers in a semiconductor when no electric field is applied?
Random with frequent changes in direction.
What is the motion of carriers in a semiconductor when an electric field is applied?
Random but a net motion along the direction of the field.
Give equations for the drift velocity and mobility of electrons and holes.
Check slide 69
At high fields in Si, there is a limit to the speed of carriers, what is this?
Fast moving carriers generate phonons and so lose energy.
At high fields in GaAs, there is a maximum velocity that falls away, why is this?
The electrons get excited into a secondary minimum in the GaAs band structure that is close to the first. The effective mass is larger in this minimum thus the electrons slow down.
Why is the mobility of electrons increased at low temperatures from lattice vibration scattering (electron-phonon interactions)?
Little thermal energy Few phonons Carrier velocity (thermal) is small Mean scattering times are large Hence µ is high
Why is the mobility of electrons lowered at high temperatures from lattice vibration scattering (electron-phonon interactions)?
More thermal energy Many phonons Large thermal velocities Mean scattering times are small Hence µ is low
What is the approximate relationship between µ and temperature as a result of electron-phonon scattering?
µ proportional 1/T^1.5
Why is the mobility of electrons lowered at low temperatures from impurity scattering (electron-phonon interactions)?
The carrier velocity (thermal) is small so electrons are easily deflected by ionised impurities.
The time between scattering events is small so µ is small
Why is the mobility of electrons increased at high temperatures from impurity scattering (electron-phonon interactions)?
The carrier velocity (thermal) is high so electrons are less easily deflected by ionised impurities.
The time between scattering events is greater so µ increases.
What is the approximate relationship between µ and temperature as a result of ionised impurity scattering?
µ proportional T^1.5
State a relationship between overall µ, µ(lattice) and µ(impurity).
1/µ = 1/µ(lattice) + 1/µ(impurity)
Which of µ(lattice) and µ(impurity) controls the overall µ?
Which ever is smaller is there one that controls the overall µ
In an n-ype material, how does concentration affect the type of scattering?
At low conc of dopant, the scattering is mostly lattice scattering whereas at high conc it is mostly ionised impurity scattering.
In a p-ype material, how does concentration affect the type of scattering?
At low conc of dopant, the scattering is mostly lattice scattering whereas at high conc it is mostly ionised impurity scattering.
Does mobility vary the same amount with concentration in both n and p-type materials?
No, the variation is much greater in n-type materials as holes have a lower effective mass so have lower mobilities and stay low.
Derive an expression for the conductivity of a material in terms of number of carriers and mobility.
Check slide 79
Sketch how conductivity varies with temperature and concentration of dopant for an n-type material giving reasons for the shape.
Check slide 81
What happens in recombination?
An electron and hole recombine (electron from conduction band and hole in valence band) releasing energy equivalent to the band gap.
What happens in generation?
Energy is input (minimum is band gap energy) promoting an electron to the conduction band and generating a hole in the valence band. It is the generation of an electron-hole pair.
Justify the law of mass action.
Check slide 83
What happens to the law of mass action under non-equilibrium conditions when there is carrier injection?
np > n(i)^2
What happens to the law of mass action under non-equilibrium conditions when there is carrier extraction?
np < n(i)^2
If there is a non-equilibrium variation in carrier concentration, and conc varies as a function of position, what will happen?
A diffusion crurent will be set up.
State expressions for the diffusion currents for electrons and holes.
Check slide 85
Under equilibrium conditions will the diffusion current will flow?
No. The diffusion current will be matched by an equal and opposite drift current.