sediments Flashcards
sediments basic principles
- settling particles transport pollutant into lakes/lake sediments
- in undisturbed sediments, depth represents time scale
- to interpret data, we must know smth about sedimentary processes (ex redox, stability..)
components of sediments
- solid (detrital material, non dtrital material OM, 2ndary mrnls)
- pore water (may occupy >95% of volume)
chemical analysis of solid sediment
toal analysis : all mineral phases dissolved in one step in a strong acid, gives total elt C°
sequential leaching of sediment : dissolved in several steps using diff reagents, each one dissolves different solid components
oxic/anoxic sediments
oxic sediemnts : where oxygen is dissolved in the pore water, top mm/cm = Brown Fe and Mn are stare here
anoxic = no oxygen, consumed in decomposition of OM? Sulphites are stables, black sediments (FeS)
sediment rates
- mg accumulate sediment/cm2/year
- mm accumulated sediment/year=> affected by the compaction of the sediments with increasing depth
depletion rate
- if mg/cm2:year : D =S * C
- if mm/year : D = S(1-n)phoC
- S = sedimentation rate, C = C° in sedimenting material, pho = density, n = porosity
diffusion in pore waters
transport of elts in pore water
Fick’s first law:
J = -nD*deltaC/deltaZ
J in ug/cm2/year, n = porosity, D = diff coeff (cm2/year) delta = C° gratient in pore water (ug/cm2)
diffusion of elt always from higher to lower C°
sediments as environmental archives prerequisites
- cst and known sedimentatio accumulation rate
- sediment must be undisturbed by bottom currents
- investigated elt mut be immobile, not diff in pore waters