Section 10 chemical equilibrium Flashcards

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1
Q

Equilibrium definition

A

Where in a reversible reaction the forwards and backwards reactions both occur at a constant rate.

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2
Q

Dynamic equilibrium definition

A

Where in a reversible reaction both the forwards and backwards reaction occur at the same constant rate.

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3
Q

Difference between dynamic equilibrium and equilibrium

A

Dynamic equilibrium will constantly occur and reactants and products must be at equal concentration.

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4
Q

Concentration effect on equilibrium

A

As the concentration of a chemical increases the reaction shifts in the opposite direction.
As the concentration of a chemical decreases the reaction shifts in the direction of the chemical being removed.

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5
Q

Temperature effect on equilibrium

A

As the temperature increases the reaction will shift towards the endothermic reaction.
As the temperature decreases the reaction will shift towards the exothermic reaction

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6
Q

Catalyst effect on equilibrium

A

Use of a catalyst speeds up the rate of both reactions, forwards and backwards, this is due to the activation energy decreasing, this has no overall effect on the reaction equilibrium.

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7
Q

Pressure effect on equilibrium

A

High/increase pressure causes the reaction to shift towards and favour the reaction with less moles as products.
Low/decrease pressure causes the reaction to shift towards the reaction with more moles as products.

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8
Q

Rules of pressure in equilibrium

A

Pressure in equilibrium only affects gas
Equal number of moles means the reaction isn’t affected by pressure.

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