Section 10 chemical equilibrium Flashcards
Equilibrium definition
Where in a reversible reaction the forwards and backwards reactions both occur at a constant rate.
Dynamic equilibrium definition
Where in a reversible reaction both the forwards and backwards reaction occur at the same constant rate.
Difference between dynamic equilibrium and equilibrium
Dynamic equilibrium will constantly occur and reactants and products must be at equal concentration.
Concentration effect on equilibrium
As the concentration of a chemical increases the reaction shifts in the opposite direction.
As the concentration of a chemical decreases the reaction shifts in the direction of the chemical being removed.
Temperature effect on equilibrium
As the temperature increases the reaction will shift towards the endothermic reaction.
As the temperature decreases the reaction will shift towards the exothermic reaction
Catalyst effect on equilibrium
Use of a catalyst speeds up the rate of both reactions, forwards and backwards, this is due to the activation energy decreasing, this has no overall effect on the reaction equilibrium.
Pressure effect on equilibrium
High/increase pressure causes the reaction to shift towards and favour the reaction with less moles as products.
Low/decrease pressure causes the reaction to shift towards the reaction with more moles as products.
Rules of pressure in equilibrium
Pressure in equilibrium only affects gas
Equal number of moles means the reaction isn’t affected by pressure.