Section 1 Flashcards

1
Q

First ionisation energy

A

energy needed to remove 1 mole of electrons from 1 mole of gaseous atoms

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2
Q

The lower the ionisation energy the ____

A

easier to form an ion

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3
Q

Ionisation energy

nuclear charge

A

The more protons in the nucleus, the more positive charge there is and the stronger the attraction for the electrons

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4
Q

Ionisation energy

Atomic radius

A

An electron closer will be more strongly attracted

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5
Q

Ionisation energy

shielding

A

The more shielding, the less attraction between outer shell electrons and nucleus

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6
Q

Ionisation energy down the group trend

A

gets smaller because as you go down there are more shells that increases atomic radius and increases shielding

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7
Q

Ionisation energy across a period

A

get larger because there are more protons, higher nuclear charge and small radius

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8
Q

Ionisation energy across period

sometimes vary why?

A

due to electrons being in different types of orbitals

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9
Q

Second ionisation energy

A

energy needed to remove 1 electron from each ion in 1 mole of gaseous +1 ions to form 1 mole of gaseous 2+ ions

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10
Q

graphite structure

A

flat hexagons covalently bonded with three bonds

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11
Q

Graphite structure properties

A

weak forces between layers - sheets can slide
delocalised electrons allow current to flow
insoluble in any solvent - bonds to hard to break
high melting point
low density

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12
Q

diamond properties due to structure

A

high melting point
very hard
wont dissolve in solvent
cant conduct electricity

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13
Q

graphene properties

A

very strong
conducts electricity
transparent and light

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14
Q

metallic bonding

mp and bp

A

the more electrons the stronger the bonds so the higher the mp and bp

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15
Q

metallic bonding

ability to be shaped

A

no ions holding bonds together so ions can slide over each other

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16
Q

metallic bonding

conductivity

A

good thermal conductors

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17
Q

metallic bonding

solubility

A

insoluble because

18
Q

metals across a period

A

bp and mp increase across period because ions have greater charge
increasing number of delocalised electrons
higher charge density

19
Q

simple molecular structures

mp and bp

A

weak induced dipole-dipole forces

20
Q

Group 2

As you go down group 2 __________- decreases and ___________ increases

A

ionisation energy

reactivity

21
Q

Group 2

reaction with water

A

metal hydroxide and hydrogen

22
Q

Group 2

Be reaction with water

A

doesn’t react

23
Q

Group 2

reaction with oxygen

A

solid white oxides

24
Q

Group 2

oxide exception

A

Magnesium
slow reaction - hydroxide insoluble
hydroxides are more soluble down the group so solution gets more alkali

25
Group 2 | reaction with dilute acid
Hydrogen and metal acid thing
26
Group 2 | uses
calcium hydroxide to neutralise soil | magnesium hydroxide to neutralise stomach acid
27
`Group 7 | F
pale yellow | gas
28
Group 7 | Cl
green | gas
29
Group 7 | Br
red brown liquid
30
Group 7 | I
grey | solid
31
Group 7 | bp and mp down grouo
increase due to stronger induced dipole-dipole as number of electrons increases
32
Group 7 | down the group the halogens become less ___
oxidising
33
Group 7 | iodine water colour
brown
34
Disproportionation
when a single element is simultaneously oxidised and reduced
35
Disproportionation | making bleach
2NaOH + Cl2 -> NaClO + NaCl +H2O
36
Disproportionation | mixing chlorine and water
Cl2 + H2O HCl + HClO | chloric acid
37
Disproportionation | chloric acid making chlorate ions
HClO + H2O ClO- + H3O+
38
Disproportionation | chlorine alternative
Ozone kills bacteria - expensive UV kills bacteria but inaffective in cloudy water doesn't prevent contamination further down the line
39
Tests | suphate
barium nitrate solution | white precipitate
40
Tests | halides
add nitric acid and silver nitrate solution c b i
41
Tests for ammonia
add NaOH heat damp litmus paper blue