SCIENCE CHEMISTRY (Sec3): Chpt5_Physical properties of ionic substances, simple covalent & giant covalent substances Flashcards

1
Q

physical properties of ionic substances [5 pts]

A
  1. high m.p.s and b.p.s
  2. excellent conductor of electricity in molten or aqueous state
  3. insulator of electricity in solid state
  4. solubility
  5. hard but brittle
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2
Q

high m.p.s and b.p.s (ionic substances) [2pts]

A
  • electrostatic forces of attraction: very strong
  • require more energy to overcome it
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3
Q

excellent conductor of electricity in molten or aqueous state (ionic substances) [3pts]

A
  • ions can move about in molten (liquid state) and aqueous state
  • giant ionic lattice structure has broken down
  • electricity is conducted when ions move around freely
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4
Q

insulator of electricity in solid state (ionic substances) [2pts]

A
  • ions cannot move around
  • held strongly at fixed positions by ionic bonds in giant lattice structure
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5
Q

solubility (ionic substances) [2pts]

A
  • most ionic compounds soluble in water to form aqueous state
  • insoluble in organic solvents
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6
Q

hard but brittle (hard - ionic substances) [2pts]

A
  • electrostatic forces of attraction bwt. oppositely charged ions hold them strongly together
  • ionic compounds can resist deforming: ions cannot move easily
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7
Q

hard but brittle (brittle - ionic substances) [3pts]

A
  • strong force applied on ionic compounds: cause ions to shift away from their lattice positions
  • ions of same charge approach each other: repel one another
  • repulsive forces become greater than attractive forces: lattice structure broken down
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8
Q

physical properties of covalent substances (covalent bonding) [3pts]

A
  1. low m.p. and low b.p.
  2. cannot conduct electricity at any state generally
  3. solubility
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9
Q

cannot conduct electricity at any state generally (covalent substances) [2pts]

A
  • most simple covalent molecules neutral molecules: do not have ions or delocalised electrons
  • certain covalent molecules can dissociate in water to produce mobile ions to conduct electricity (e.g. hydrochloric acid)
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9
Q

low m.p. and b.p. (covalent substances) [4pts]

A
  • intermolecular force bwt. molecules is very weak: less energy required to overcome it
  • some simple covalent molecules evaporate easily: volatile (exist as liquids or gases at room temp.)
  • m.p. and b.p. increases when molecules get larger
  • intermolecular forces of attraction become stronger: more energy needed to overcome them
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10
Q

solubility (covalent substances) [1pt]

A

most simple covalent molecules are soluble in organic solvents but not in water

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11
Q

properties of diamond (giant covalent substances) [4pts]

A
  1. extremely high m.p.s and b.p.s
  2. cannot conduct electricity
  3. very hard
  4. solubility
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12
Q

extremely high m.p.s and b.p.s (properties of diamond) [1pt]

A

network of strong covalent bonds: large amount of energy is required to break these strong bonds

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13
Q

cannot conduct electricity (properties of diamond) [1pt]

A

does not have delocalised electrons or mobile ions to conduct electricity

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14
Q

very hard (properties of diamond) [1pt]

A

contains many strong covalent bonds only that requires a large amount of energy to break structure apart

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15
Q

solubility (properties of diamond) [1pt]

A

most giant covalent substances cannot dissolve in water & in organic solvents

16
Q

graphite [1pt]

A

made of layers of planes which consist of carbon atoms joining together in a form of hexagonal rings

17
Q

properties of graphite (giant covalent structure) [4pts]

A
  1. high m.p. and b.p.
  2. can conduct electricity
  3. solubility
  4. soft and slippery
18
Q

high m.p. and b.p. (properties of graphite) [1pt]

A

network of strong covalent bonds: large amount of energy required to break these strong bonds

19
Q

can conduct electricity (properties of graphite) [3pts]

A
  • each carbon atom covalently bonded to three other carbon atoms only
  • one electron from each atom which is not bonded: delocalised electron
  • delocalised electron able to move around freely
20
Q

solubility (properties of graphite) [1pt]

A

most giant covalent substances cannot dissolve in water & in organic solvents

21
Q

soft and slippery (properties of graphite) [2pts]

A
  • each layer held by weak intermolecular force of attraction that can be overcomed easily by small amount of energy
  • layers able to slide over one another easily: soft and slippery
22
Q

macromolecules [4pts]

A
  • covalent substances
  • polymers: made by joining many covalent molecules into chains of much larger molecules
  • natural polymers (e.g. silk, wool, starch, rubber)
  • man-made polymers (e.g. nylon, polystyrene, polyester)
23
Q

properties of macromolecules [3pts]

A
  1. low m.p. and b.p.
  2. cannot conduct electricity in any state
  3. solubility
24
low m.p. and b.p. (properties of macromolecules) [2pts]
- do not have fixed m.p. and b.p. (can be formed by molecules of diff. sizes) - tend to soften over a range of temp.s when molecular vibrations with higher k.e. overcomes weaker intermolecular forces of attraction
25
cannot conduct electricity in any state (properties of macromolecules) [1pt]
do not have delocalised electrons or mobile ions
26
solubility (properties of macromolecules) [1pt]
insoluble in water but soluble in organic solvents