SC10-11-12-13 Flashcards
What is electrolysis?
The breaking down of a substance using electricity.
An electric current is passed through an electrolyte causing it to decompose.
What occurs in electrolysis?
Oxidation
Reduction
OIL - RIG
What happens to the positive ions in electrolysis?
The positive ions (cations) in the electrolyte move towards the cathode (negative electrode) and are reduced (gain electrons).
What is a cathode and anode?
Cathode = negative electrode.
Anode = positive electrode.
What are cations and anions?
Cations = positive ions
Anions = negative ions
What happens to the negative ions in electrolysis?
The negative ions (anions) in the electrolyte move towards the anode (positive electrode) and are oxidised (lose electrons).
Why cant an ionic solid be electrolysed?
Because the ions are in fixed positions and cant move.
Why can a molten ionic compound be electrolysed?
Because the ions can move freely and conduct electricity.
What are positive metal ions reduced to?
Metal atoms at the cathode.
What are negative ions oxidised to?
Atoms or molecules at the anode.
What is the reactivity series?
Its a table that lists metals in order of their reactivity.
What are the elements in the reactivity series of metals?
Potassium - please Sodium - stop Calcium - calling Magnesium - me Aluminium - a (Carbon) - crazy Zinc - zebra Iron - I Tin - totally Lead - like Copper - chewing Silver - stripey Gold - grass
What is the pattern in the metal reactivity series?
Most reactive - least reactive
Least resistant to oxidisation - most resistant to oxidisation.
What does potassium, sodium and calcium form when they react with cold water?
Hydrogen and metal hydroxide.
What happens when K, Na and Ca react with acid?
React violently.
What forms when magnesium, aluminium, zinc and iron react with water?
Reacts slowly
Reacts with steam to form hydrogen and metal oxide.
What forms when magnesium, aluminium, zinc and iron react with acid?
Form hydrogen and a salt solution.
What is a redox reaction?
A reaction where oxidation and reduction occur.
Displacement.
What happens in displacement reactions?
A more reactive element reacts to take the place of a less reactive element in a compound.
In metal displacement reactions, the more reactive metal loses electrons and the less reactive metal gains electrons.
So the more reactive metal is oxidised and the less reactive is reduced (redox).
What is a metal ore?
Its a rock which contains enough metal to age it economically worthwhile extracting the metal from it.
How can metals be extracted from ores?
Reduction with carbon
Electrolysis
Bioleaching
Phytoextraction
How do you know what method of extraction to use?
If its higher than carbon in the reactivity series then electrolysis.
If its below carbon than reduction with carbon.
How does electrolysis work?
Once the metal ore is melted, an electric current is passed through it.
The metal is discharged at the cathode and the non-metal at the anode.