S.1.3.6 and S.1.3.7 Ionization Energies Flashcards
Limit of convergence
Corresponds to the ionization energy
Ionization energy
Minimum amount of energy required to remove 1 mole of electrons from the ground state of 1 mole of gaseous atoms
H (g) –> H⁺ (g) + e⁻
When does ionization occur?
When change in frequency is 0
Ionization energy for one atom
E = hf
For 1 mole: E = hf/mol
What gives information about electron configuration?
Successive ionization energy data
From left to right across a period, ionization energies…
Generally increase
More energy is required to remove an electron from an atom because of an increase in the electrostatic force of attraction between nucleus and outer electrons
Down a group, ionization energy…
Decreases
Less energy is required to remove outer electrons that are farther away from the attractive pull of the nucleus
What provides further evidence for the existence of sublevels?
Regular discontinuities in the trend across the period
Successive ionization energies
More energy required to remove second and successive electrons from an atom because the number of protons exceeds the number of remaining electrons while the electron-electron repulsion decreases
Electron clouds are pulled closer to the nucleus and held tighter by increased electrostatic attraction