rxns organic chem Flashcards
reactions of alkanes
combustion and substitution
reaction of alkene/alkyne
add two atom or groups to a multiple bond, turning it to a single bond; hydrogenation, halogenation, hydrohalogenation
alcohol reactions
substitution, acid-catalyzed elimination, addition
combustion
CxHy + (x+y/4)O2 -> XCO2 + y/2 H2O
substitution
CH4 + CL2 (or F2, Br2) -> CH3Cl + HCl
hydrogenation
adding H2 to make alkanes
halogenation
adding Cl2 or Br2 to
hydrohalogenation
add HF/HCl/HBr/Hi; which ever carbon has more H attached is one that receives H, fewer H receives halogen
substitution (alcohol)
CH3OH + HCl -> CH3Cl + H2O
acid-catalyzed elimination
CH3CH2OH (H2SO4) -> CH2=CH2 + H2O; addition is opposite
oxidizing/reducing of groups
alakne -> alkohol -> aldehyde -> carboxylic acid
OX inc. ->
<- RED inc.
ketone/aldehyde addition of C=O
polar molecules add across the C=O of aldehydes/ketones, + part attaching to O, O single bonded
ester condensation rxns
acid + alcohol -> ester + water
what is an ester made of
carboxylic acid and alcohol
are ethers reactive?
no unreactive, good solvents