rheology Flashcards
what is a newtonian fluid
the rate of flow of the fluid (y) is directly propionate to the applied stress
what is the equation for relative viscosity
nr = n/no
nr = relative viscosity
n = the viscosity of solution
no = relative to the solvent
what is the equation for specific viscosity
nsp = nr -1
what is the equation for reduced viscosity or the viscosity number
k= nsp/ c
k = reduced viscosity
nsp = specific viscosity
c = mass concerntrattion of solution (g/cm^3)
how do you determine the viscosity of a newtonian fluid
glass capillary viscometers
- where the time taken for the fluid to pass through the dashed line is measure. then using the HAGEN - POISEUILLE EQUATION
- disadvantages are that it is time consuming, can not be automated and no control of shear
falling sphere viscometer
-the viscosity it’s measured through STOKES LAW where it is rearranged to make n the subject
Rotational viscometers
- the viscosity is measured by measuring the torque and turning speed - this can be easily measured at different rates
what are some examples of newtonian fluids
water
ethanol
what are non newtonian fluids
the viscosity of the fluid is dependant on the shear, the shear stress and the shear rate
what are the types of newtonian fluids
- plastic bingham flow
- psuedoplstic
- dilantancy
what is plastic bingham flow
- a bingham plastic does not flow until. field stress is applied
for example plastic
what is pseudo plastic
- this is when shear thinking occurs - the viscosity reduced
the viscosity reduces with added sheer
the gradient is curved and then plato’s near the need
when low sheer - the polymer chains re tangled and are ,ore viscous
when there is high shear the polymer chains are untangled and it is less viscous
and example is polymer gels
what is dilatancy
- shear thickening
the gradient (which is viscosity) is low then rises
the viscosity increases with added shear
when there is low shear the particles are dispersed a
when there is high shear the particles are forced l together making it more viscous
an example is concerntrated suspension such as corn starch
what is the power law
- it is able to tell us whether a fluid is newtonian, psuedoplastic, dilatancy
if the flow of behaviour index (n) is
1= newtonian fluid
1 or more = psuedoplastic
1 or less = dilatancy
what is time dependant behaviour
- the flow of some materials is dependant on the time
teh changes i the structure of the material may not occur immediately
what are the w different types of rheomsteer testing
- flow - to measure high shear, in single direction
- creep - to measure shear in a single push and in a single direction - this is for low shear
- oscillatory - to measure shear, this is in both directions - back and fourth at low shear rate
what is the difference between spring and dash[ot
- spring - this is when maximum force is applied making sure that it is below the specific yield point - so that no bonds are broken, it will experience stress and once that strain is gone it will immediately return to its original position
- dashpot - when strain is applied it will not return to its original position and will rather stay in teh position that it originally was in