reverible reactions, industrial processes and important chemicals Flashcards

1
Q

what is meant by a reversible reaction

A

a reaction that can occur in 2 directions

the products can react to form the original reactants
A+B ⇌ C+D

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2
Q

for A+B ⇌ C+D which are the products for:
forward reaction
backwards reaction

A

C+D is forward

A+B is backward

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3
Q

how can the direction of a reversible reaction be changed

A

by changing the conditions:

Pressure

temperature

concentration of reactants or products

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4
Q

If the reaction is exothermic, will the backwards reaction be endothermic or exothermic

A

Exothermic, the same amount of energy is transferred

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5
Q

What is the reaction in the harbour process

symbol equation

A

Nitrogen + symbol hydrogen ⇌ ammonia

N2+3H2 ⇌ 2NH3

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6
Q

What can ammonia be used for

A

To produce nitrogen-based fertilisers

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7
Q

what can nitrogen and hydrogen gas be a obtained from

A

Nitrogen can be obtained from the air

hydrogen Gas can be obtained from natural gas or other sources

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8
Q

What are the conditions required for the harbour process

A

High temperature (450°C)

High pressure (200 atm)

Iron catalyst

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9
Q

What happens during the harbor process

A
  1. purified gases passed over the iron catalyst
  2. Some nitrogen and hydrogen reacts to form ammonia
  3. Some ammonia breaks down into nitrogen and hydrogen (because reaction is reversible)
  4. The mixture is called, ammonia liquefies and is removed
  5. The remaining nitrogen and hydrogen is recycled
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10
Q

What are the disadvantages of using a low temperature and a very high pressure

A

Low temperature causes slower rate of reaction

High pressure requires high energy

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11
Q

What are two things that want to be maximised when choosing the conditions of the have a process

A

The rate of reaction and the yield of ammonia

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12
Q

How can the presence of ammonia gas be tested

A

Moist red litmus paper will turn blue as ammonia is alkaline

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13
Q

What are the advantages of using fertilisers

A

Increasing crop yields and growth

increase profit for farmers

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14
Q

What are the disadvantages of using fertilisers

A

It changes the pH of soil

can cause baby blue syndrome

many stages in manufacture

eutrophication my fertilisers are washed into rivers and lakes
Increase of nitrate and phosphate importer encourage algae growth
Algae bloom blocks sunlight from water plants underneath
Water plants die and are broken down by bacteria
Oxygen is used up by bacteria, killing other living organisms in the water

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15
Q

what is the contact process

A

the manufacture of sulfuric acid

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16
Q

what is the first stage of the contact process

A

sulfur is burned in air and reacts with oxygen to form sulfur dioxide

S + O2 —> SO2
(L) (g) (g)

16
Q

what is the second step of the contact process

A

Sulphur dioxide is then oxidised (with the help of a catalyst) to make sulphur trioxide

SO2 + O2 ⇌ SO3

17
Q

what is the final stage of the contact process

A

Oleum is then made by dissolving sulphur trioxide and concentrated sulphuric acid. The oleum is then converted to sulphuric acid by adding water

18
Q

which stage in the contact process is reversible

A

the second stage

19
Q

What are the uses of sulphuric acid

A

Most are used to make fertiliser

Manufacturers of chemicals (examples: HCl, dyes, plastics, detergent and paints)|

Processing metals

20
Q

What does dehydrating agent do

A

Removes water from other compounds

21
Q

How does concentrated sulphuric acid aact as a dehydrating agent with sugar

A

Concentrated sulphuric acid remove six water molecules per glucose (C6 H12 O6) molecule

Highly exothermic reaction

What are molecules released as steam and a black mass of carbon forms

22
Q

What change can be observed when concentrated sulphuric acid acts as a dehydrating agent on hydrated copper (II) sulphate

A

Blue crystals (heated copper sulphate) —> White powder (anhydrous copper sulfate)