crude oil, fuels and organic chemistry Flashcards

1
Q

what is crude oil

A

a finite resource found in rocks, formed over millions of years from the remains of simple marine organisms
it contains a complex mixture of hydrocarbons

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2
Q

what are the processes in the fractional. distillation of crude oil

A

the crude oil mixture is put into the fractionating column at the bottom and he dead

The hydrocarbons evaporate and rise at the column

As the hydrocarbons rise, they eventually reach a fraction which is cool enough for them to condense back into a liquid

Mitchell left in the bottom which does not evaporate at all it’s called bitumen

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3
Q

what are fractions in fractional distillation

A

fractions contain mixtures of hydrocarbons (alkanes) with similar boiling points

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4
Q

what are the trends in properties of fractions with increasing chain length

A
boiling and melting points increases 
viscosity increases 
flammability increases 
volatility increases 
their colour darkens 
their usefulness as fuel decreases
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5
Q

what is the economic importance of the oil industry

A

Oil companies set the price of oil so there is an influence globally on the economy – it can be hard for poor countries to buy oil

wars or internal crisis within the country that produce oil can affect the flow of oil to other countries which they sell to

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6
Q

what is the political importance of the oil industry

A

Countries that are large producers of oil can essentially cut off all the supplies to other countries

This is used as a political tool

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7
Q

what is the social impact of the oil industry

A

the oil industry supplies jobs and money to the economy

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8
Q

what are the environmental impacts of the oil industry

A

burning fossil fuels release large amounts of carbon dioxide side, a greenhouse gas, into the atmosphere, contributing to global warming and climate change

Oil spillages into the ocean result in the death of marine life and birds and are often dealt with by setting them alight

Building of power stations and the process of drilling for oil causes damage to the landscape and loss of habitats

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9
Q

what are the combustion reactions of hydrocarbons

A

When hydrocarbon to be in plenty of oxygen it will come past as follows:
hydrocarbon + oxygen
—> carbon dioxide + water

When hydrocarbons being with insufficient oxygen it will come past as follows:
Hydrocarbon + oxygen —> carbon monoxide + water

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10
Q

what is the combustion reaction of hydrogen and what are its uses

A

hydrogen burns in oxygen and forms water

hydrogen is used as a fuel in rockets and some cars

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10
Q

what are the advantages of using hydrogen as a fuel

A

no greenhouse gases are produced in the combustion of hydrogen

an alternative fuel option as current fuels are running out

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11
Q

what are the disadvantages of using hydrogen as a fuel

A

hydrogen is extremely flammable

most of hydrogen produced comes from the fossil fuels or electrolysis so it still has a negative impact on the environment

hard to store and transport - must be cooled to very low temperatures so it liquifies for storage and transport

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12
Q

what is the fire triangle

A

a symbol that contains 3 things needs for a fire to burn: oxygen, fuel and heat

removing any of these will cause the fire to stop burning, so knowledge of the fire triangle can be used to prevent and put out fires

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13
Q

what is hydrocarbon cracking

A

breaking long chain hydrocarbons down into shorter and more useful chains

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14
Q

what are the products of hydrocarbon cracking

A

alkanes and unsaturated hydrocarbons called alkenes

alkenes are monomers that are used to make plastics

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15
Q

what is the general formula of alkanes

A

Cn H2n +2

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16
Q

what is the general formula of alkenes

A

Cn H2n

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17
Q

what are some examples of simple alkenes

A
methane - CH4
ethane  - C2H6
propane - C3H8
butane - C4H10
pentane - C5H12
18
Q

what are some examples of simple alkanes

A

ethene - C2H4
propene - C3H6
butene - C4H8

19
Q

what is isomerism

A

when two compounds have the same molecular formula (same number and type of each atom) but their structures differ is some way

20
Q

what is isomerism in alkanes

A

the main carbon chain length differs but the molecule still has the same number

21
Q

what is isomerism in alkenes

A

the position of the double bond in the molecules can differ but the molecular structure stays the same

22
Q

how do you name complex alkanes and alkenes

A

Locate the longest continuous linear chain carbon atoms

Number the carbon atoms from the end closest to a functional group or branch point

Alphabetically Leicester functional groups attached to the carbon chain and stay at the cabin number the group is attached to me

Put up a band count the position of the double pump accounting bonds not carbon atoms

23
Q

what are the addition reactions

A

reactions in which two or more molecules combine to form a larger one with no other products

24
Q

what is the test for alkenes

A

bromine in water is an orange solution and when shaken with an alkene bromine water will decolourise as the bromine reacts with the alkene to form substituted alkanes - this is an addition reaction

25
Q

what is addition polymerisation

A

Alkanes can be used to make polymers

Polymers a large
molecule is made up of repeating units called monomers

Alkanes can be polymerised because they have double bond that open up to connect to other alkene
monomers in a chain

Example: polyethene is formed from ethene monomer

26
Q

what are the uses of polyethene

A

bin liners
plastic bottles
hoses and tubes
plastic bags

27
Q

what are the uses of poly(propene)

A

plastic for cars
packaging
textiles

28
Q

what are the uses of polyvinyl chloride (PVC)

A

water pipes
electrical wires
window panes
medical tubing and IV bags

29
Q

what are the uses of poly(tetrafluoroethene)

PTFE

A

coating non-stick pans
nail polish
coating hair straighteners and curlers

30
Q

what are the general properties of polymers

A

thermosoftening polymers melt when heated and can be remoulded and reshaped

thermosetting polymers do not melt when heated

high-density polymers tend to be harder and stronger than low density polymers

31
Q

what are the environmental issues relating to the disposal of plastics

A

plastics are non-biodegradable

increasing pressure on landfill sites for waste disposal

32
Q

what are methods for disposing plastics

A

landfill sites

incineration disposal - however this releases carbon dioxide, a greenhouse gas

recycling - this manages the other issues of disposal, provides jobs and helps preserve the non-renewable source of crude oil

33
Q

how is ethanol produced

A

the fermentation of sugar using yeast - the enzymes in the yeast catalyse the reaction

glucose —> ethanol + carbon dioxide

34
Q

what is the test for alcohol

A

add a few drops of sulfuric acid and potassium dichromate solution to the sample

gently heat

if alcohol is present the solution will change from orange to green

35
Q

what are the uses of ethanol

A

found in alcoholic drinks

as a fuel

as a solvent - it dissolves a large number of substances easily

36
Q

what are the social impacts of alcoholic drinks

A

bad for health and causes a number of illnesses including liver disease, cancers and cardiovascular problems

it can increase the number of violent fights and other crimes

37
Q

what are the economic impacts of alcholic drinks

A

the alcohol industry provides jobs

costs the economy due to healthcare and police costs from alcohol-related issues

37
Q

what are the advantages of using ethanol as a fule

A

it is a carbon neutral fuel - no net addition of carbon dioxide into the atmosphere

good fuel alternative for countries without their own crude oil supply

renewable source - made from sugar cane

38
Q

what are the disadvantages of using bioethanol as a fuel

A

Energy is needed in growing sugar canes, distillation and transport of ethanol which will require the burning of fossil fuels so it will still cause global warming

Engine must be altered before they can use bioethanol as fuel

Can cause deforestation to provide land for growing sugarcane

Using food as fuel can increase food prices

Some areas of the world and not hot enough and do not have enough light hours in the day to be able to completely switch to biofule

39
Q

how do you name alcohols

A

The suffix -ol which is preceded by the number of the cup and the hydroxyl (OH) functional group is attached to

If there are multiple alcohol functional groups the suffix becomes –diol, –triol, –tetrol

40
Q

what are the potential isomers of alcohols

A

Isomers are compounds which have the same molecular formula but different structural formula

This means isomers of alcohol have the same molecular formula but the -OH alcohol group is positioned at a different carbon atom thus giving the compound a different structural formula

41
Q

what is the microbial oxidation of ethanol

A

When ethanol is oxidised it forms ethanoic acid, a carboxylic acid which has the functional group -COOH

The oxidation can be carried out by microbes

other alcohols can undergo microbial oxidation to form carboxylic acids

An oxygen atom is gained and hydrogen atoms are reduced

42
Q

what is infrared spectroscopy

graphs

A

A experimental technique that can be used to work out the structure of a compound or molecule

When infrared light is shone at a compound, its bonds absorb some of the infrared light

Different font absorbed at different frequency of infrared light

By identifying different peaks, functional groups in the compound can be identified