Rev-period 3, Isomers,bonding Flashcards

1
Q

Phosphorus oxide reacts with water

A

Phosphoric acid
H3PO4
Acidic

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2
Q

Sodium trioxide plus water

A

Sulfuric acid
Tetrahedral
109.5

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3
Q

sodium dioxide plus water

A

Sulfurous acid h2SO4
Trigonal pyramidal
109.5

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4
Q

Electro negativity

A

Power of an atom to attract the two electrons in a covalent bond

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5
Q

Si structure

A

Macromolecular

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6
Q

P4 structure

A

Simple molecular

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7
Q

S8

A

Simple molecular

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8
Q

Cl

A

Simple molecular

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9
Q

Ar

A

Monomatomic

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10
Q

Na o + h20 observations

A

Yellow flame and white solid

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11
Q

Mg o + H20

A

White powder and flame
Fast in steam

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12
Q

Al o

A

White flame

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13
Q

Si o

A

White flame

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14
Q

P4 o

A

Stored in water
Bright white

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15
Q

S8 acidic

A

Blue
Chocking gas

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16
Q

What oxides are insoluble

A

Al
Si
Sort of mg

17
Q

What oxides dissolve in water

A

S-acidic
N’a

18
Q

What oxides are violent

A

So3
P

19
Q

What oxide is amphoteric

A

Al

20
Q

Hydrogen bonding

A

Strongest
N O F
Donating lone pair

21
Q

Dipole dipole bonding

A

Attractive forces between polar elements

22
Q

How do Van der waals work

A

In a non polar molecule the electron charge cloud moves forming an instantaneous dipole
As this dipole approaches a non polar molecule there is repulsion causing the molecules charges to shift forming an induced dipole and then there is an attraction which is the imf

23
Q

What are the three structural isomers

A

Chain
Positional
Functional

24
Q

What are the two stereo isomers

A

E/z
Optical

25
Q

Symmetrical

A

All bonds identical and no line pairs
Not polar so dipoles cancel out

26
Q

Structural isomer

A

Same molecular formula but different structures

27
Q

Functional isomers

A

Same formula different functional group

28
Q

Atom economy

A

Desired product over total times 100

29
Q

Optical isomer

A

1c with 4 groups
Chiral
Super imposeable mirror image

30
Q

What is race mate

A

50/50 mix

31
Q

Polarimeter

A

Monochromatic

32
Q

Percentage yield

A

Actual/theoretical moles x100

33
Q

Why is theoretical mass lower than actual mass

A

Incomplete reactions
Reactants left on apparatus
Side reactions
Reversible reaction

34
Q

E/z isomérisation scaffold

A

Look at lhs carbon
Most protons=priority group
Same side - z
Opposite - e
Repeat for rhs

35
Q

Stereoisomers

A

Same atoms connected
Differently arranged in space

36
Q

Geometric isomerism

A

Double bond
E opposites
Zame
Different chemical and physical properties

37
Q

Chain isomerism

A

Same molecular formula
Longest hydrocarbon chain changes due to branches