Physical Flashcards
What is a nucleon
Sub atomic particles in the nucleus
RAM Ar definition
The average mass of an atom compared to 1/12th the mass of carbon 12
RMM Mr
The average mass of a molecule compared to 1/12th the mass of carbon 12
How to calculate RAM with isotopes
Isotopic mass x percentage)+(isotopic mass x percent)/100
Mass spectrometry stages(4)
1 Ionise-remove electron= positive ion
2 Acceleration- accelerates ions in electric field
-same kE for all ions
-ions with lower mass=higher acceleration
3 ion drift-ions enter region with no electrical field and drift
-ions with lower mass drift at higher speeds
4 Detection-ions with lower mass reach detector first
Electrospray
-Dissolved in volatile solvent
-injected as an aerosol through a needle
-needle has high positive charge
-sample gains H+ ion (proton)
-forms MH+ ion
Electron impact
-high energy electrons
- electron gun
-fired at sample
-knocks off electron= gains electron
Detector -ToF
-Detector consists of a negatively charged plate
-Positive ions reach detector+become discharged by drawing an electron from the detector
- creating a current
-detector is connected to a computer which records time of particular ion to reach it
First ionisation energy is
The energy needed to remove 1 electron from each atom in 1 mole of gaseous atoms to form 1 mole of gaseous ions
Spectator ion
Doesn’t ppt in reaction
Limiting reactant
Runs out first and determines product made