Rest: Materials Flashcards
Includes composite, bonding to enamel/dentine.
COMPOSITE
What are the five components of composite ?
- Glass filler particles i.e. alumina, silica, borosilicate.
- Resin i.e. BisGMA.
- Photoinitiator i.e. camphorquinoine.
- Silane coupling agent.
- Low weight dimethacrylates i.e. TEGDMA.
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COMPOSITE
What is the benefits/disadvanatges of smaller filler particle size vs. large ?
- Small filler particles - better aesthetics, poorer mechanical properties.
- Large filler particles - better mechnical properties, likely to stain and poorer aesthetics.
COMPOSITE
What is the function of resin ?
- Resin is involved in setting reaction.
- Long monomer chains with C=C.
- Undergoes activation by photoinitiator.
- Causes free radical polymerisation.
- Crosslinking occurs generating monomer growth.
- Which results in increased viscosity and mechnical properties.
- Hydrophobic end also bonds with DBA.
COMPOSITE
What is the purpose of camphorquinoine ?
- Photoinitiator.
- Acivtated by blue light.
- Causes release of free radical which initiates free radical polymerisation of resin.
- Resulting in increased molecular weight, viscosity and mechnical properties.
Always some unreacted monomer - risk of leaching and pulp irritation.
COMPOSITE
What is the purpose of silane coupling agent ?
- Removes moisture from the surface of glass particles which allows resin and glass particle bonding.
- Methoxy group hydrolyses hydroxy group.
COMPOSITE
What is the purpose of low weight dimethacrylates ?
Changes viscosity and polymerisation rate.
COMPOSITE
What is the standard depth of cure for composite ?
2mm.
Knoop Hardness Test (ISO 4049).
COMPOSITE
What problems can arise which might affect light cure systems ?
- Premature setting due to dental light.
- Optimistic depth of cure (use increments - 2mm).
- Polymerisation shrinkage (risk of cuspal fracture and microleakage).
COMPOSITE
List some benefical properties of enamel.
Aesthetics. Smooth surface. Biocompatible. Anticariogenic. Radiopaque. Low thermal diffusivity and conductivity. Similar mechnical properties to dentine.
COMPOSITE
What is the biggest disadvantage with composite’s properties ?
- High thermal expansion coefficient.
- High polymerisation contraction.
BONDING SYSTEMS - COMPOSITE TO ENAMEL/DENTINE
Bonding to enamel - what material is used ?
37% phosphoric acid.
BONDING SYSTEMS - COMPOSITE TO ENAMEL/DENTINE
How does acid etch improve bonding to enamel ?
- Etch roughens long enamel prisms containing hydroxyapetite crystals - changing the structure to a ‘keyhole’ appearance.
- Etch also increases the surface energy of enamel by removing the smear layer and increases surface wettability.
- This allows micromechnical bonding of resin through interlocking.
BONDING SYSTEMS - COMPOSITE TO ENAMEL/DENTINE
Explain why bonding to dentine is more difficult than bonding to enamel.
- Non-inert surface and continuously releases water which prevents flow of DBA into the dentinal tubules and results in low surface energy.
- There are also varying sizes/densities of dentinal tubules.
- Also has smear layer.
BONDING SYSTEMS - COMPOSITE TO ENAMEL/DENTINE
What properties should dentine bonding agent have ?
- Low viscosity.
- Able to make intimate contact with dentine.
- Allow adhesion with resin.
BONDING SYSTEMS - COMPOSITE TO ENAMEL/DENTINE
In what two ways does dentine bonding agent facilitate bonding between resin and tooth surface ?
- Allows for interlocking forming mechnical bond.
- Molecular entanglement occurs forming chemical bond.