Researching Chemistry Flashcards

1
Q

What is a stoichiometric equation

A

A balanced equation

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2
Q

When is a reaction described as being quantative

A

When the substances react completely according to the mole ratios in balanced equation

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3
Q

When can gravimetric analyse be used

A
  • when a reaction goes to completion

- when an insoluble product (precipitate) is formed

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4
Q

What are the key properties of product formed from gravimetric analyse

A
  • low solubility
  • easy to filter
  • product must be stable at -105 c
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5
Q

Why might there be differences between theory and experiment

A
  • mass transfer losses
  • purity of reactant is less than 100%
  • reaction was incomplete
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6
Q

What is gravimetric analysis

A

The use of accurate measurements of mass to determine something about an unknown

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7
Q

Describe the technique of drying to constant mass

A
  • repeatedly heat a sample and cool in desiccator

- until successive weighings are +/- 0.01g

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8
Q

Why is a desiccator used

A

To prevent the sample absorbing moisture from the air whilst cooling

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9
Q

What is volumetric analysis

A

Uses accurate measurements of volumes to determine the concentration (composition) of a solution

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10
Q

What is a standard solution

A

A solution of accurately known concentration

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11
Q

What are the key properties of a primary standard

A
  • very high purity
  • stable in air and solution
  • high relative formula mass
  • soluble in water
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12
Q

What are the three main types of titration

A
  • acid base
  • redox
  • complexometric (EDTA)
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13
Q

Why is the choice of indicator important in an acid base titration

A

The pH range in which it changed is critical

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14
Q

What type of titration is used to analyse solutions of transition metal ions

A

Complexometric

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15
Q

What is a back titration

A

Titration method where the concentration of an analyte is determined by reacting it with a known amount of excess reagent

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16
Q

It is undesirable to accept titre values which are ?

A

Very low (less than 6cm^3)

17
Q

What is an accurate measurement

A

One that is in close agreement with the true or accepted value

18
Q

When is a measurement precise

A

When they are in close agreement with each other

19
Q

What does the phrase - weighing approximately 6.0g accurately mean

A
  • the mass should be close to 6.0g

- but must be measured accurately (eg 5.890)

20
Q

What is colorimetry

A

An analytical technique used to determine the concentration of coloured substances in solution

21
Q

What is an empirical formula

A

The simplest ratio of atoms present in a substance found by experiment

22
Q

What technique is used to purify chemicals

A

Recrystallisation

23
Q

What is TLC (thin layer chromatography) used for

A

Used to separate non-volatile mixtures

24
Q

How would the Rf value be calculated

A

Distance moved by compound / distance moved by solvent